Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores

Room temperature phosphorescence (RTP) is a topic which is currently widely studied, but a study on the correlation between types of molecular solid and RTP properties is lacking. Here the authors show that RTP is enhanced in the racemic form of axial chiral molecules due to its denser R- and S- cro...

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Autores principales:	Xiugang Wu, Chun-Ying Huang, Deng-Gao Chen, Denghui Liu, Chichi Wu, Keh-Jiunh Chou, Bin Zhang, Yafei Wang, Yu Liu, Elise Y. Li, Weiguo Zhu, Pi-Tai Chou
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/23dc15c4fc664d1990e9a4d09404cf72
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spelling	oai:doaj.org-article:23dc15c4fc664d1990e9a4d09404cf722021-12-02T16:56:31ZExploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores10.1038/s41467-020-15976-52041-1723https://doaj.org/article/23dc15c4fc664d1990e9a4d09404cf722020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15976-5https://doaj.org/toc/2041-1723Room temperature phosphorescence (RTP) is a topic which is currently widely studied, but a study on the correlation between types of molecular solid and RTP properties is lacking. Here the authors show that RTP is enhanced in the racemic form of axial chiral molecules due to its denser R- and S- cross packing arrangement.Xiugang WuChun-Ying HuangDeng-Gao ChenDenghui LiuChichi WuKeh-Jiunh ChouBin ZhangYafei WangYu LiuElise Y. LiWeiguo ZhuPi-Tai ChouNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiugang Wu Chun-Ying Huang Deng-Gao Chen Denghui Liu Chichi Wu Keh-Jiunh Chou Bin Zhang Yafei Wang Yu Liu Elise Y. Li Weiguo Zhu Pi-Tai Chou Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
description	Room temperature phosphorescence (RTP) is a topic which is currently widely studied, but a study on the correlation between types of molecular solid and RTP properties is lacking. Here the authors show that RTP is enhanced in the racemic form of axial chiral molecules due to its denser R- and S- cross packing arrangement.
format	article
author	Xiugang Wu Chun-Ying Huang Deng-Gao Chen Denghui Liu Chichi Wu Keh-Jiunh Chou Bin Zhang Yafei Wang Yu Liu Elise Y. Li Weiguo Zhu Pi-Tai Chou
author_facet	Xiugang Wu Chun-Ying Huang Deng-Gao Chen Denghui Liu Chichi Wu Keh-Jiunh Chou Bin Zhang Yafei Wang Yu Liu Elise Y. Li Weiguo Zhu Pi-Tai Chou
author_sort	Xiugang Wu
title	Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
title_short	Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
title_full	Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
title_fullStr	Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
title_full_unstemmed	Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
title_sort	exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate wallach’s rule in the lighting chiral chromophores
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/23dc15c4fc664d1990e9a4d09404cf72
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Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores

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