Electric field-induced crystallization of ferroelectric hafnium zirconium oxide
Abstract Ferroelectricity in crystalline hafnium oxide thin films is strongly investigated for the application in non-volatile memories, sensors and other applications. Especially for back-end-of-line (BEoL) integration the decrease of crystallization temperature is of major importance. However, an...
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Nature Portfolio
2021
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oai:doaj.org-article:240560cdb6e64b16966221ef786dd2c82021-11-21T12:23:44ZElectric field-induced crystallization of ferroelectric hafnium zirconium oxide10.1038/s41598-021-01724-22045-2322https://doaj.org/article/240560cdb6e64b16966221ef786dd2c82021-11-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-01724-2https://doaj.org/toc/2045-2322Abstract Ferroelectricity in crystalline hafnium oxide thin films is strongly investigated for the application in non-volatile memories, sensors and other applications. Especially for back-end-of-line (BEoL) integration the decrease of crystallization temperature is of major importance. However, an alternative method for inducing ferroelectricity in amorphous or semi-crystalline hafnium zirconium oxide films is presented here, using the newly discovered effect of electric field-induced crystallization in hafnium oxide films. When applying this method, an outstanding remanent polarization value of 2P $$_{\mathrm{R}}$$ R = 47 $$\upmu$$ μ C/cm $$^{2}$$ 2 is achieved for a 5 nm thin film. Besides the influence of Zr content on the film crystallinity, the reliability of films crystallized with this effect is explored, highlighting the controlled crystallization, excellent endurance and long-term retention.Maximilian LedererSukhrob AbdulazhanovRicardo OlivoDavid LehningerThomas KämpfeKonrad SeidelLukas M. EngNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-7 (2021) |
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Medicine R Science Q Maximilian Lederer Sukhrob Abdulazhanov Ricardo Olivo David Lehninger Thomas Kämpfe Konrad Seidel Lukas M. Eng Electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
description |
Abstract Ferroelectricity in crystalline hafnium oxide thin films is strongly investigated for the application in non-volatile memories, sensors and other applications. Especially for back-end-of-line (BEoL) integration the decrease of crystallization temperature is of major importance. However, an alternative method for inducing ferroelectricity in amorphous or semi-crystalline hafnium zirconium oxide films is presented here, using the newly discovered effect of electric field-induced crystallization in hafnium oxide films. When applying this method, an outstanding remanent polarization value of 2P $$_{\mathrm{R}}$$ R = 47 $$\upmu$$ μ C/cm $$^{2}$$ 2 is achieved for a 5 nm thin film. Besides the influence of Zr content on the film crystallinity, the reliability of films crystallized with this effect is explored, highlighting the controlled crystallization, excellent endurance and long-term retention. |
format |
article |
author |
Maximilian Lederer Sukhrob Abdulazhanov Ricardo Olivo David Lehninger Thomas Kämpfe Konrad Seidel Lukas M. Eng |
author_facet |
Maximilian Lederer Sukhrob Abdulazhanov Ricardo Olivo David Lehninger Thomas Kämpfe Konrad Seidel Lukas M. Eng |
author_sort |
Maximilian Lederer |
title |
Electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
title_short |
Electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
title_full |
Electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
title_fullStr |
Electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
title_full_unstemmed |
Electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
title_sort |
electric field-induced crystallization of ferroelectric hafnium zirconium oxide |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/240560cdb6e64b16966221ef786dd2c8 |
work_keys_str_mv |
AT maximilianlederer electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide AT sukhrobabdulazhanov electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide AT ricardoolivo electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide AT davidlehninger electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide AT thomaskampfe electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide AT konradseidel electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide AT lukasmeng electricfieldinducedcrystallizationofferroelectrichafniumzirconiumoxide |
_version_ |
1718419052323405824 |