Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
A detailed study of the preparation of poly and single crystals of the MnCr2S4 ternary spinel and their structural and magnetic characterisation are reported. X-ray diffraction data for the polycrystals show a nearly stoichiometric chemical composition and a normal spinel structure of the main phase...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2016
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oai:doaj.org-article:2415129f2d9c416b8368f5daf16682cc2021-11-21T11:57:12ZSynthesis, crystal structure, and magnetic properties of MnCr2S4 spinel537.6222537-63651810-648Xhttps://doaj.org/article/2415129f2d9c416b8368f5daf16682cc2016-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2016/article/50378https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365A detailed study of the preparation of poly and single crystals of the MnCr2S4 ternary spinel and their structural and magnetic characterisation are reported. X-ray diffraction data for the polycrystals show a nearly stoichiometric chemical composition and a normal spinel structure of the main phase with an additional reflection (1%) of the minor phase MnS. From the temperature dependence of susceptibility measured in field-cooled (FC) and zero-field cooled (ZFC) sequences, the Curie temperature of TC = 65 K is determined; it coresponds to a transition from the paramagnetic to ferrimagnetically ordered state. The second magnetic transition is detected at TYK = 5 K; it coresponds to a transition from a coliniar to triangular spin configuration of the Yafet–Kittel type. Prodan, LilianD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 15, Iss 3-4, Pp 125-129 (2016) |
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Physics QC1-999 Electronics TK7800-8360 |
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Physics QC1-999 Electronics TK7800-8360 Prodan, Lilian Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel |
description |
A detailed study of the preparation of poly and single crystals of the MnCr2S4 ternary spinel and their structural and magnetic characterisation are reported. X-ray diffraction data for the polycrystals show a nearly stoichiometric chemical composition and a normal spinel structure of the main phase with an additional reflection (1%) of the minor phase MnS. From the temperature dependence of susceptibility measured in field-cooled (FC) and zero-field cooled (ZFC) sequences, the Curie temperature of TC = 65 K is determined; it coresponds to a transition from the paramagnetic to ferrimagnetically ordered state. The second magnetic transition is detected at TYK = 5 K; it coresponds to a transition from a coliniar to triangular spin configuration of the Yafet–Kittel type. |
format |
article |
author |
Prodan, Lilian |
author_facet |
Prodan, Lilian |
author_sort |
Prodan, Lilian |
title |
Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel |
title_short |
Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel |
title_full |
Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel |
title_fullStr |
Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel |
title_full_unstemmed |
Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel |
title_sort |
synthesis, crystal structure, and magnetic properties of mncr2s4 spinel |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2016 |
url |
https://doaj.org/article/2415129f2d9c416b8368f5daf16682cc |
work_keys_str_mv |
AT prodanlilian synthesiscrystalstructureandmagneticpropertiesofmncr2s4spinel |
_version_ |
1718419352052563968 |