Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel

A detailed study of the preparation of poly and single crystals of the MnCr2S4 ternary spinel and their structural and magnetic characterisation are reported. X-ray diffraction data for the polycrystals show a nearly stoichiometric chemical composition and a normal spinel structure of the main phase...

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Autor principal: Prodan, Lilian
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Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2016
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Acceso en línea:https://doaj.org/article/2415129f2d9c416b8368f5daf16682cc
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spelling oai:doaj.org-article:2415129f2d9c416b8368f5daf16682cc2021-11-21T11:57:12ZSynthesis, crystal structure, and magnetic properties of MnCr2S4 spinel537.6222537-63651810-648Xhttps://doaj.org/article/2415129f2d9c416b8368f5daf16682cc2016-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2016/article/50378https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365A detailed study of the preparation of poly and single crystals of the MnCr2S4 ternary spinel and their structural and magnetic characterisation are reported. X-ray diffraction data for the polycrystals show a nearly stoichiometric chemical composition and a normal spinel structure of the main phase with an additional reflection (1%) of the minor phase MnS. From the temperature dependence of susceptibility measured in field-cooled (FC) and zero-field cooled (ZFC) sequences, the Curie temperature of TC = 65 K is determined; it coresponds to a transition from the paramagnetic to ferrimagnetically ordered state. The second magnetic transition is detected at TYK = 5 K; it coresponds to a transition from a coliniar to triangular spin configuration of the Yafet–Kittel type. Prodan, LilianD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 15, Iss 3-4, Pp 125-129 (2016)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Prodan, Lilian
Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
description A detailed study of the preparation of poly and single crystals of the MnCr2S4 ternary spinel and their structural and magnetic characterisation are reported. X-ray diffraction data for the polycrystals show a nearly stoichiometric chemical composition and a normal spinel structure of the main phase with an additional reflection (1%) of the minor phase MnS. From the temperature dependence of susceptibility measured in field-cooled (FC) and zero-field cooled (ZFC) sequences, the Curie temperature of TC = 65 K is determined; it coresponds to a transition from the paramagnetic to ferrimagnetically ordered state. The second magnetic transition is detected at TYK = 5 K; it coresponds to a transition from a coliniar to triangular spin configuration of the Yafet–Kittel type.
format article
author Prodan, Lilian
author_facet Prodan, Lilian
author_sort Prodan, Lilian
title Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
title_short Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
title_full Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
title_fullStr Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
title_full_unstemmed Synthesis, crystal structure, and magnetic properties of MnCr2S4 spinel
title_sort synthesis, crystal structure, and magnetic properties of mncr2s4 spinel
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2016
url https://doaj.org/article/2415129f2d9c416b8368f5daf16682cc
work_keys_str_mv AT prodanlilian synthesiscrystalstructureandmagneticpropertiesofmncr2s4spinel
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