Evidence for single metal two electron oxidative addition and reductive elimination at uranium

The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within...

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Autores principales: Benedict M. Gardner, Christos E. Kefalidis, Erli Lu, Dipti Patel, Eric J. L. McInnes, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/2523f3b2e85c4ba3aef12ee29f04b159
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spelling oai:doaj.org-article:2523f3b2e85c4ba3aef12ee29f04b1592021-12-02T14:42:17ZEvidence for single metal two electron oxidative addition and reductive elimination at uranium10.1038/s41467-017-01363-02041-1723https://doaj.org/article/2523f3b2e85c4ba3aef12ee29f04b1592017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01363-0https://doaj.org/toc/2041-1723The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.Benedict M. GardnerChristos E. KefalidisErli LuDipti PatelEric J. L. McInnesFloriana TunaAshley J. WoolesLaurent MaronStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Benedict M. Gardner
Christos E. Kefalidis
Erli Lu
Dipti Patel
Eric J. L. McInnes
Floriana Tuna
Ashley J. Wooles
Laurent Maron
Stephen T. Liddle
Evidence for single metal two electron oxidative addition and reductive elimination at uranium
description The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.
format article
author Benedict M. Gardner
Christos E. Kefalidis
Erli Lu
Dipti Patel
Eric J. L. McInnes
Floriana Tuna
Ashley J. Wooles
Laurent Maron
Stephen T. Liddle
author_facet Benedict M. Gardner
Christos E. Kefalidis
Erli Lu
Dipti Patel
Eric J. L. McInnes
Floriana Tuna
Ashley J. Wooles
Laurent Maron
Stephen T. Liddle
author_sort Benedict M. Gardner
title Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_short Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_full Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_fullStr Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_full_unstemmed Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_sort evidence for single metal two electron oxidative addition and reductive elimination at uranium
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/2523f3b2e85c4ba3aef12ee29f04b159
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