Evidence for single metal two electron oxidative addition and reductive elimination at uranium

The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within...

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Main Authors:	Benedict M. Gardner, Christos E. Kefalidis, Erli Lu, Dipti Patel, Eric J. L. McInnes, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
Format:	article
Language:	EN
Published:	Nature Portfolio 2017
Subjects:	Science Q
Online Access:	https://doaj.org/article/2523f3b2e85c4ba3aef12ee29f04b159
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spelling	oai:doaj.org-article:2523f3b2e85c4ba3aef12ee29f04b1592021-12-02T14:42:17ZEvidence for single metal two electron oxidative addition and reductive elimination at uranium10.1038/s41467-017-01363-02041-1723https://doaj.org/article/2523f3b2e85c4ba3aef12ee29f04b1592017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01363-0https://doaj.org/toc/2041-1723The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.Benedict M. GardnerChristos E. KefalidisErli LuDipti PatelEric J. L. McInnesFloriana TunaAshley J. WoolesLaurent MaronStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Benedict M. Gardner Christos E. Kefalidis Erli Lu Dipti Patel Eric J. L. McInnes Floriana Tuna Ashley J. Wooles Laurent Maron Stephen T. Liddle Evidence for single metal two electron oxidative addition and reductive elimination at uranium
description	The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.
format	article
author	Benedict M. Gardner Christos E. Kefalidis Erli Lu Dipti Patel Eric J. L. McInnes Floriana Tuna Ashley J. Wooles Laurent Maron Stephen T. Liddle
author_facet	Benedict M. Gardner Christos E. Kefalidis Erli Lu Dipti Patel Eric J. L. McInnes Floriana Tuna Ashley J. Wooles Laurent Maron Stephen T. Liddle
author_sort	Benedict M. Gardner
title	Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_short	Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_full	Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_fullStr	Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_full_unstemmed	Evidence for single metal two electron oxidative addition and reductive elimination at uranium
title_sort	evidence for single metal two electron oxidative addition and reductive elimination at uranium
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/2523f3b2e85c4ba3aef12ee29f04b159
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Evidence for single metal two electron oxidative addition and reductive elimination at uranium

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