Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage

Studying the nature of actinide-actinide bonds is important for understanding the electronic structure of the 5f elements, but the synthesis of these chemical bonds remains extremely challenging. Here, the authors report a strong covalent Th-Th bond formed between two rarely accessible Th3+ ions, st...

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Autores principales: Jiaxin Zhuang, Roser Morales-Martínez, Jiangwei Zhang, Yaofeng Wang, Yang-Rong Yao, Cuiying Pei, Antonio Rodríguez-Fortea, Shuao Wang, Luis Echegoyen, Coen de Graaf, Josep M. Poblet, Ning Chen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/2560ea86b141464d8518b55dc75195bd
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Sumario:Studying the nature of actinide-actinide bonds is important for understanding the electronic structure of the 5f elements, but the synthesis of these chemical bonds remains extremely challenging. Here, the authors report a strong covalent Th-Th bond formed between two rarely accessible Th3+ ions, stabilized inside a fullerene cage.