Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage

Studying the nature of actinide-actinide bonds is important for understanding the electronic structure of the 5f elements, but the synthesis of these chemical bonds remains extremely challenging. Here, the authors report a strong covalent Th-Th bond formed between two rarely accessible Th3+ ions, st...

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Autores principales:	Jiaxin Zhuang, Roser Morales-Martínez, Jiangwei Zhang, Yaofeng Wang, Yang-Rong Yao, Cuiying Pei, Antonio Rodríguez-Fortea, Shuao Wang, Luis Echegoyen, Coen de Graaf, Josep M. Poblet, Ning Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2560ea86b141464d8518b55dc75195bd
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spelling	oai:doaj.org-article:2560ea86b141464d8518b55dc75195bd2021-12-02T17:33:40ZCharacterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage10.1038/s41467-021-22659-22041-1723https://doaj.org/article/2560ea86b141464d8518b55dc75195bd2021-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22659-2https://doaj.org/toc/2041-1723Studying the nature of actinide-actinide bonds is important for understanding the electronic structure of the 5f elements, but the synthesis of these chemical bonds remains extremely challenging. Here, the authors report a strong covalent Th-Th bond formed between two rarely accessible Th3+ ions, stabilized inside a fullerene cage.Jiaxin ZhuangRoser Morales-MartínezJiangwei ZhangYaofeng WangYang-Rong YaoCuiying PeiAntonio Rodríguez-ForteaShuao WangLuis EchegoyenCoen de GraafJosep M. PobletNing ChenNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jiaxin Zhuang Roser Morales-Martínez Jiangwei Zhang Yaofeng Wang Yang-Rong Yao Cuiying Pei Antonio Rodríguez-Fortea Shuao Wang Luis Echegoyen Coen de Graaf Josep M. Poblet Ning Chen Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage
description	Studying the nature of actinide-actinide bonds is important for understanding the electronic structure of the 5f elements, but the synthesis of these chemical bonds remains extremely challenging. Here, the authors report a strong covalent Th-Th bond formed between two rarely accessible Th3+ ions, stabilized inside a fullerene cage.
format	article
author	Jiaxin Zhuang Roser Morales-Martínez Jiangwei Zhang Yaofeng Wang Yang-Rong Yao Cuiying Pei Antonio Rodríguez-Fortea Shuao Wang Luis Echegoyen Coen de Graaf Josep M. Poblet Ning Chen
author_facet	Jiaxin Zhuang Roser Morales-Martínez Jiangwei Zhang Yaofeng Wang Yang-Rong Yao Cuiying Pei Antonio Rodríguez-Fortea Shuao Wang Luis Echegoyen Coen de Graaf Josep M. Poblet Ning Chen
author_sort	Jiaxin Zhuang
title	Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage
title_short	Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage
title_full	Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage
title_fullStr	Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage
title_full_unstemmed	Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage
title_sort	characterization of a strong covalent th3+–th3+ bond inside an i h (7)-c80 fullerene cage
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/2560ea86b141464d8518b55dc75195bd
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Characterization of a strong covalent Th3+–Th3+ bond inside an I h (7)-C80 fullerene cage

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