Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions

Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions

Fluorine-containing moieties show significant effects in improving the properties of functional molecules. Here the authors show diazaphospholene-catalyzed hydrodefluorination of trifluoromethylalkenes to chemoselectively construct gem-difluoroalkenes and terminal monofluoroalkenes by simple adjustm...

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Autores principales: Jingjing Zhang, Jin-Dong Yang, Jin-Pei Cheng
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/258e26d5614e4c298754b5c68c98cab6
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spelling oai:doaj.org-article:258e26d5614e4c298754b5c68c98cab62021-12-02T16:50:25ZChemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions10.1038/s41467-021-23101-32041-1723https://doaj.org/article/258e26d5614e4c298754b5c68c98cab62021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23101-3https://doaj.org/toc/2041-1723Fluorine-containing moieties show significant effects in improving the properties of functional molecules. Here the authors show diazaphospholene-catalyzed hydrodefluorination of trifluoromethylalkenes to chemoselectively construct gem-difluoroalkenes and terminal monofluoroalkenes by simple adjustment of the reactant stoichiometry.Jingjing ZhangJin-Dong YangJin-Pei ChengNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jingjing Zhang
Jin-Dong Yang
Jin-Pei Cheng
Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
description Fluorine-containing moieties show significant effects in improving the properties of functional molecules. Here the authors show diazaphospholene-catalyzed hydrodefluorination of trifluoromethylalkenes to chemoselectively construct gem-difluoroalkenes and terminal monofluoroalkenes by simple adjustment of the reactant stoichiometry.
format article
author Jingjing Zhang
Jin-Dong Yang
Jin-Pei Cheng
author_facet Jingjing Zhang
Jin-Dong Yang
Jin-Pei Cheng
author_sort Jingjing Zhang
title Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
title_short Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
title_full Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
title_fullStr Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
title_full_unstemmed Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
title_sort chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/258e26d5614e4c298754b5c68c98cab6
work_keys_str_mv AT jingjingzhang chemoselectivecatalytichydrodefluorinationoftrifluoromethylalkenestowardsmonogemdifluoroalkenesundermetalfreeconditions
AT jindongyang chemoselectivecatalytichydrodefluorinationoftrifluoromethylalkenestowardsmonogemdifluoroalkenesundermetalfreeconditions
AT jinpeicheng chemoselectivecatalytichydrodefluorinationoftrifluoromethylalkenestowardsmonogemdifluoroalkenesundermetalfreeconditions
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