Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue

Carbonyl complexes have been studied extensively thanks to their rich substitution and redox chemistry, but most homoleptic transition metal carbonyl complexes isolated in the condensed phase are neutral or anionic. Here, the authors isolate two homoleptic carbonyl radical cations in the condensed p...

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Autores principales:	Jan Bohnenberger, Wolfram Feuerstein, Daniel Himmel, Michael Daub, Frank Breher, Ingo Krossing
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2604cc7a944e4c2ebc2fee62d30c7e7c
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spelling	oai:doaj.org-article:2604cc7a944e4c2ebc2fee62d30c7e7c2021-12-02T14:40:20ZStable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue10.1038/s41467-019-08517-22041-1723https://doaj.org/article/2604cc7a944e4c2ebc2fee62d30c7e7c2019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08517-2https://doaj.org/toc/2041-1723Carbonyl complexes have been studied extensively thanks to their rich substitution and redox chemistry, but most homoleptic transition metal carbonyl complexes isolated in the condensed phase are neutral or anionic. Here, the authors isolate two homoleptic carbonyl radical cations in the condensed phase; both 17-electron [Cr(CO)6]•+ salts.Jan BohnenbergerWolfram FeuersteinDaniel HimmelMichael DaubFrank BreherIngo KrossingNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jan Bohnenberger Wolfram Feuerstein Daniel Himmel Michael Daub Frank Breher Ingo Krossing Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue
description	Carbonyl complexes have been studied extensively thanks to their rich substitution and redox chemistry, but most homoleptic transition metal carbonyl complexes isolated in the condensed phase are neutral or anionic. Here, the authors isolate two homoleptic carbonyl radical cations in the condensed phase; both 17-electron [Cr(CO)6]•+ salts.
format	article
author	Jan Bohnenberger Wolfram Feuerstein Daniel Himmel Michael Daub Frank Breher Ingo Krossing
author_facet	Jan Bohnenberger Wolfram Feuerstein Daniel Himmel Michael Daub Frank Breher Ingo Krossing
author_sort	Jan Bohnenberger
title	Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue
title_short	Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue
title_full	Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue
title_fullStr	Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue
title_full_unstemmed	Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue
title_sort	stable salts of the hexacarbonyl chromium(i) cation and its pentacarbonyl-nitrosyl chromium(i) analogue
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/2604cc7a944e4c2ebc2fee62d30c7e7c
work_keys_str_mv	AT janbohnenberger stablesaltsofthehexacarbonylchromiumicationanditspentacarbonylnitrosylchromiumianalogue AT wolframfeuerstein stablesaltsofthehexacarbonylchromiumicationanditspentacarbonylnitrosylchromiumianalogue AT danielhimmel stablesaltsofthehexacarbonylchromiumicationanditspentacarbonylnitrosylchromiumianalogue AT michaeldaub stablesaltsofthehexacarbonylchromiumicationanditspentacarbonylnitrosylchromiumianalogue AT frankbreher stablesaltsofthehexacarbonylchromiumicationanditspentacarbonylnitrosylchromiumianalogue AT ingokrossing stablesaltsofthehexacarbonylchromiumicationanditspentacarbonylnitrosylchromiumianalogue
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Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue

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