New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor

Abstract A quartz crystal adsorbent coated with 5,10,15,20-tetrakis(4-methylphenyl) porphyrin was used to examine the complexation phenomenon of three metallic ions [aluminum(III), iron(III) and indium(III)]. The aim is to select the appropriate adsorbate for metalloporphyrin fabrication. The equili...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Haifa Alyousef, Badriah M. Alotaibi, Mohamed Ben Yahia, Meznah M. Alanazi, Norah A. Alsaif
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/2610b02a4c654c6da97d230f7bb64e4a
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:2610b02a4c654c6da97d230f7bb64e4a
record_format	dspace
spelling	oai:doaj.org-article:2610b02a4c654c6da97d230f7bb64e4a2021-12-02T14:30:40ZNew insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor10.1038/s41598-021-87773-z2045-2322https://doaj.org/article/2610b02a4c654c6da97d230f7bb64e4a2021-04-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-87773-zhttps://doaj.org/toc/2045-2322Abstract A quartz crystal adsorbent coated with 5,10,15,20-tetrakis(4-methylphenyl) porphyrin was used to examine the complexation phenomenon of three metallic ions [aluminum(III), iron(III) and indium(III)]. The aim is to select the appropriate adsorbate for metalloporphyrin fabrication. The equilibrium adsorption isotherms of tetrakis(4-methylphenyl) porphyrin were performed at four temperatures (from 300 to 330 K) through the quartz crystal microbalance (QCM) method. Subsequently, the experimental data were analyzed in order to develop a thorough explanation of the complexation mechanisms. The experimental results indicated that the aluminum(III) chloride is the adequate material for metalloporphyrin application. Theoretical investigation was established through physics adsorption models in order to analyze the experimental isotherms. The AlCl3 isotherms were modeled via a single-layer adsorption model which is developed using the ideal gas law. Whereas, the FeCl3 isotherms were interpreted via a single-layer adsorption which includes the lateral interactions parameters (real gas law), indicating the lowest stability of the formed iron-porphyrin complex. The participation of the chloride ions in the double-layers adsorption of InCl3 was interpreted via layer by layer formulation. Interestingly, the physicochemical investigation of the three adopted models indicated that the tetrakis(4-methylphenyl) porphyrin adsorption was an endothermic process and that the aluminum(III) chloride can be recommended for an industrial application because it presents the highest adsorption energy (chemical bonds with porphyrins).Haifa AlyousefBadriah M. AlotaibiMohamed Ben YahiaMeznah M. AlanaziNorah A. AlsaifNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Haifa Alyousef Badriah M. Alotaibi Mohamed Ben Yahia Meznah M. Alanazi Norah A. Alsaif New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
description	Abstract A quartz crystal adsorbent coated with 5,10,15,20-tetrakis(4-methylphenyl) porphyrin was used to examine the complexation phenomenon of three metallic ions [aluminum(III), iron(III) and indium(III)]. The aim is to select the appropriate adsorbate for metalloporphyrin fabrication. The equilibrium adsorption isotherms of tetrakis(4-methylphenyl) porphyrin were performed at four temperatures (from 300 to 330 K) through the quartz crystal microbalance (QCM) method. Subsequently, the experimental data were analyzed in order to develop a thorough explanation of the complexation mechanisms. The experimental results indicated that the aluminum(III) chloride is the adequate material for metalloporphyrin application. Theoretical investigation was established through physics adsorption models in order to analyze the experimental isotherms. The AlCl3 isotherms were modeled via a single-layer adsorption model which is developed using the ideal gas law. Whereas, the FeCl3 isotherms were interpreted via a single-layer adsorption which includes the lateral interactions parameters (real gas law), indicating the lowest stability of the formed iron-porphyrin complex. The participation of the chloride ions in the double-layers adsorption of InCl3 was interpreted via layer by layer formulation. Interestingly, the physicochemical investigation of the three adopted models indicated that the tetrakis(4-methylphenyl) porphyrin adsorption was an endothermic process and that the aluminum(III) chloride can be recommended for an industrial application because it presents the highest adsorption energy (chemical bonds with porphyrins).
format	article
author	Haifa Alyousef Badriah M. Alotaibi Mohamed Ben Yahia Meznah M. Alanazi Norah A. Alsaif
author_facet	Haifa Alyousef Badriah M. Alotaibi Mohamed Ben Yahia Meznah M. Alanazi Norah A. Alsaif
author_sort	Haifa Alyousef
title	New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
title_short	New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
title_full	New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
title_fullStr	New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
title_full_unstemmed	New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
title_sort	new insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/2610b02a4c654c6da97d230f7bb64e4a
work_keys_str_mv	AT haifaalyousef newinsightsonmicroscopicpropertiesofmetalporphyrincomplexesattachedtoquartzcrystalsensor AT badriahmalotaibi newinsightsonmicroscopicpropertiesofmetalporphyrincomplexesattachedtoquartzcrystalsensor AT mohamedbenyahia newinsightsonmicroscopicpropertiesofmetalporphyrincomplexesattachedtoquartzcrystalsensor AT meznahmalanazi newinsightsonmicroscopicpropertiesofmetalporphyrincomplexesattachedtoquartzcrystalsensor AT norahaalsaif newinsightsonmicroscopicpropertiesofmetalporphyrincomplexesattachedtoquartzcrystalsensor
_version_	1718391179515527168

New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor

Ejemplares similares