The reversibility and first-order nature of liquid–liquid transition in a molecular liquid

The nature of the phenomenon of so-called ‘liquid-liquid transitions’ in molecular liquids is a long-standing debate. Here, the authors demonstrate the reversibility and first-order nature of the liquid-liquid transition in triphenyl phosphite via flash differential scanning calorimetry.

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Autores principales: Mika Kobayashi, Hajime Tanaka
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/26591fdac3f64daab1c3dfc85d8b77d9
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Sumario:The nature of the phenomenon of so-called ‘liquid-liquid transitions’ in molecular liquids is a long-standing debate. Here, the authors demonstrate the reversibility and first-order nature of the liquid-liquid transition in triphenyl phosphite via flash differential scanning calorimetry.