Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation
The uncontrolled and unethical release of pharmaceutical contaminants into aquatic sources have severe adversities, including the possible emergence of antimicrobial-resistant bacteria. Photocatalysis utilizing semiconductor heterostructures is a greener and sustainable option for the effective degr...
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2021
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oai:doaj.org-article:26ad4713b5ab4ebbab2bec1c1502ce392021-11-18T04:52:47ZStructural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation2666-821110.1016/j.ceja.2021.100148https://doaj.org/article/26ad4713b5ab4ebbab2bec1c1502ce392021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2666821121000648https://doaj.org/toc/2666-8211The uncontrolled and unethical release of pharmaceutical contaminants into aquatic sources have severe adversities, including the possible emergence of antimicrobial-resistant bacteria. Photocatalysis utilizing semiconductor heterostructures is a greener and sustainable option for the effective degradation of organic contaminants into relatively harmless by-products. Visible/sunlight active graphitic carbon nitride based photocatalysts have been explored for antibiotic degradation (Tetracycline, Doxycycline, Oxytetracycline, Sulfamethoxazole, Amoxicillin) owing to their excellent chemical/thermal stability, tunable photophysical properties and facile methods of synthesis. The properties were further enhanced by heterostructure formation with other compatible semiconductors, elemental/molecular doping and through the creation of hierarchically porous structures. Moreover, nanocomposite formation with high surface area porous frameworks induces adsorptive photocatalysis imparting bifunctionality and alleviating secondary remediation measures for regeneration of the catalysts. The review summarizes the efforts in developing C3N4 based systems for the effective degradation of various antibiotics. Finally, an outlook on essential improvements is forecasted.P. SuyanaPriyanka GangulyBalagopal N. NairSuresh C. PillaiU. S. HareeshElsevierarticleAntibiotic wasteCircular economyPhotocatalysisGraphitic carbon nitrideWaste to energySurface modificationChemical engineeringTP155-156ENChemical Engineering Journal Advances, Vol 8, Iss , Pp 100148- (2021) |
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Antibiotic waste Circular economy Photocatalysis Graphitic carbon nitride Waste to energy Surface modification Chemical engineering TP155-156 |
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Antibiotic waste Circular economy Photocatalysis Graphitic carbon nitride Waste to energy Surface modification Chemical engineering TP155-156 P. Suyana Priyanka Ganguly Balagopal N. Nair Suresh C. Pillai U. S. Hareesh Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation |
description |
The uncontrolled and unethical release of pharmaceutical contaminants into aquatic sources have severe adversities, including the possible emergence of antimicrobial-resistant bacteria. Photocatalysis utilizing semiconductor heterostructures is a greener and sustainable option for the effective degradation of organic contaminants into relatively harmless by-products. Visible/sunlight active graphitic carbon nitride based photocatalysts have been explored for antibiotic degradation (Tetracycline, Doxycycline, Oxytetracycline, Sulfamethoxazole, Amoxicillin) owing to their excellent chemical/thermal stability, tunable photophysical properties and facile methods of synthesis. The properties were further enhanced by heterostructure formation with other compatible semiconductors, elemental/molecular doping and through the creation of hierarchically porous structures. Moreover, nanocomposite formation with high surface area porous frameworks induces adsorptive photocatalysis imparting bifunctionality and alleviating secondary remediation measures for regeneration of the catalysts. The review summarizes the efforts in developing C3N4 based systems for the effective degradation of various antibiotics. Finally, an outlook on essential improvements is forecasted. |
format |
article |
author |
P. Suyana Priyanka Ganguly Balagopal N. Nair Suresh C. Pillai U. S. Hareesh |
author_facet |
P. Suyana Priyanka Ganguly Balagopal N. Nair Suresh C. Pillai U. S. Hareesh |
author_sort |
P. Suyana |
title |
Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation |
title_short |
Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation |
title_full |
Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation |
title_fullStr |
Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation |
title_full_unstemmed |
Structural and compositional tuning in g-C3N4 based systems for photocatalytic antibiotic degradation |
title_sort |
structural and compositional tuning in g-c3n4 based systems for photocatalytic antibiotic degradation |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://doaj.org/article/26ad4713b5ab4ebbab2bec1c1502ce39 |
work_keys_str_mv |
AT psuyana structuralandcompositionaltuningingc3n4basedsystemsforphotocatalyticantibioticdegradation AT priyankaganguly structuralandcompositionaltuningingc3n4basedsystemsforphotocatalyticantibioticdegradation AT balagopalnnair structuralandcompositionaltuningingc3n4basedsystemsforphotocatalyticantibioticdegradation AT sureshcpillai structuralandcompositionaltuningingc3n4basedsystemsforphotocatalyticantibioticdegradation AT ushareesh structuralandcompositionaltuningingc3n4basedsystemsforphotocatalyticantibioticdegradation |
_version_ |
1718424962960719872 |