Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa

Abstract. Adi DS, Hwang SW, Pramasari DA, Amin Y, Widyaningrum BA, Darmawan T, Septiana E, Dwianto W, Sugiyama J. 2020. Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa. Biodiversitas 21: 2893-2899. This study was conducted to eva...

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Autores principales: Danang Sudarwoko Adi, SUNG-WOOK HWANG, DWI AJIAS PRAMASARI, YUSUP AMIN, BERNADETA AYU WIDYANINGRUM, TEGUH DARMAWAN, ERIS SEPTIANA, WAHYU DWIANTO, JUNJI SUGIYAMA
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Publicado: MBI & UNS Solo 2020
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spelling oai:doaj.org-article:272298e2410b4014b5091c4f9844420b2021-11-22T00:40:52ZSpectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa1412-033X2085-472210.13057/biodiv/d210704https://doaj.org/article/272298e2410b4014b5091c4f9844420b2020-06-01T00:00:00Zhttps://smujo.id/biodiv/article/view/5944https://doaj.org/toc/1412-033Xhttps://doaj.org/toc/2085-4722Abstract. Adi DS, Hwang SW, Pramasari DA, Amin Y, Widyaningrum BA, Darmawan T, Septiana E, Dwianto W, Sugiyama J. 2020. Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa. Biodiversitas 21: 2893-2899. This study was conducted to evaluate and to determine the potential spectral band assignments that influenced the differentiation of normal and infected agarwood of Aquilaria microcarpa using Fourier Transform Infrared Spectroscopy (FTIR) and Fourier Transform Near-Infrared Spectroscopy (FTNIR). The results showed that the differences in band intensity on FTIR were identified as C=O stretching (lignin), COO-stretching (hemicellulose), aromatic skeletal vibration (lignin), and C-H bending vibration. The increasing absorbances of infected agarwood were supposed as the change on the wood tissues due to the releasing resinous compound. The C-O bond (aromatic alkane) and stretching (ether), C-C stretching (aromatic alkane), and C-H bond (aromatic ring) which related to the scented fragrance of agarwood have appeared on the FTIR spectra. Multivariate analysis with principal component analysis (PCA) and partial least square discriminant analysis (PLS-DA) of the second derivative NIR spectra at the wavenumber 8,000-4,000 cm-1 showed that normal and infected agarwood was successful to be separated. Discriminant model one-on-one classification exhibited good performances as the R2 performance (R2P) values was 0.99. There were eight major wood components which contributed to the separation based on NIR spectra, where lignin, hemicellulose, and xylans were the most valuable chemical compound.Danang Sudarwoko AdiSUNG-WOOK HWANGDWI AJIAS PRAMASARIYUSUP AMINBERNADETA AYU WIDYANINGRUMTEGUH DARMAWANERIS SEPTIANAWAHYU DWIANTOJUNJI SUGIYAMAMBI & UNS Soloarticleftir, ftnir, agarwood, pca, pls-daBiology (General)QH301-705.5ENBiodiversitas, Vol 21, Iss 7 (2020)
institution DOAJ
collection DOAJ
language EN
topic ftir, ftnir, agarwood, pca, pls-da
Biology (General)
QH301-705.5
spellingShingle ftir, ftnir, agarwood, pca, pls-da
Biology (General)
QH301-705.5
Danang Sudarwoko Adi
SUNG-WOOK HWANG
DWI AJIAS PRAMASARI
YUSUP AMIN
BERNADETA AYU WIDYANINGRUM
TEGUH DARMAWAN
ERIS SEPTIANA
WAHYU DWIANTO
JUNJI SUGIYAMA
Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa
description Abstract. Adi DS, Hwang SW, Pramasari DA, Amin Y, Widyaningrum BA, Darmawan T, Septiana E, Dwianto W, Sugiyama J. 2020. Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa. Biodiversitas 21: 2893-2899. This study was conducted to evaluate and to determine the potential spectral band assignments that influenced the differentiation of normal and infected agarwood of Aquilaria microcarpa using Fourier Transform Infrared Spectroscopy (FTIR) and Fourier Transform Near-Infrared Spectroscopy (FTNIR). The results showed that the differences in band intensity on FTIR were identified as C=O stretching (lignin), COO-stretching (hemicellulose), aromatic skeletal vibration (lignin), and C-H bending vibration. The increasing absorbances of infected agarwood were supposed as the change on the wood tissues due to the releasing resinous compound. The C-O bond (aromatic alkane) and stretching (ether), C-C stretching (aromatic alkane), and C-H bond (aromatic ring) which related to the scented fragrance of agarwood have appeared on the FTIR spectra. Multivariate analysis with principal component analysis (PCA) and partial least square discriminant analysis (PLS-DA) of the second derivative NIR spectra at the wavenumber 8,000-4,000 cm-1 showed that normal and infected agarwood was successful to be separated. Discriminant model one-on-one classification exhibited good performances as the R2 performance (R2P) values was 0.99. There were eight major wood components which contributed to the separation based on NIR spectra, where lignin, hemicellulose, and xylans were the most valuable chemical compound.
format article
author Danang Sudarwoko Adi
SUNG-WOOK HWANG
DWI AJIAS PRAMASARI
YUSUP AMIN
BERNADETA AYU WIDYANINGRUM
TEGUH DARMAWAN
ERIS SEPTIANA
WAHYU DWIANTO
JUNJI SUGIYAMA
author_facet Danang Sudarwoko Adi
SUNG-WOOK HWANG
DWI AJIAS PRAMASARI
YUSUP AMIN
BERNADETA AYU WIDYANINGRUM
TEGUH DARMAWAN
ERIS SEPTIANA
WAHYU DWIANTO
JUNJI SUGIYAMA
author_sort Danang Sudarwoko Adi
title Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa
title_short Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa
title_full Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa
title_fullStr Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa
title_full_unstemmed Spectral observation of agarwood by infrared spectroscopy: The differences of infected and normal Aquilaria microcarpa
title_sort spectral observation of agarwood by infrared spectroscopy: the differences of infected and normal aquilaria microcarpa
publisher MBI & UNS Solo
publishDate 2020
url https://doaj.org/article/272298e2410b4014b5091c4f9844420b
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