Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
MCD spectrum of the exchange coupled [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2] complex was analyzed. The analysis is based on the assumption that weak exchange interaction does not change the optical properties of the interacting ions and affects the saturation magnetization behavi...
Guardado en:
| Autor principal: | |
|---|---|
| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2011
|
| Materias: | |
| Acceso en línea: | https://doaj.org/article/27439fbbdc844bd0b365427f4382e133 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| Sumario: | MCD spectrum of the exchange coupled [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2] complex
was analyzed. The analysis is based on the assumption that weak exchange interaction does not
change the optical properties of the interacting ions and affects the saturation magnetization
behavior only. The feature of MCD behavior, namely, the disappearance of some lines with
increasing magnetic field and appearance again with the opposite sign, was explained by the
overlap of the electronic transitions at different but near wavelengths. |
|---|