Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.

Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.

MCD spectrum of the exchange coupled [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2] complex was analyzed. The analysis is based on the assumption that weak exchange interaction does not change the optical properties of the interacting ions and affects the saturation magnetization behavi...

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Autor principal: Ostrovschii, Serghei
Formato: article
Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2011
Materias:
Physics
QC1-999
Electronics
TK7800-8360
Acceso en línea:https://doaj.org/article/27439fbbdc844bd0b365427f4382e133
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spelling oai:doaj.org-article:27439fbbdc844bd0b365427f4382e1332021-11-21T12:02:47ZMagnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer. 2537-63651810-648Xhttps://doaj.org/article/27439fbbdc844bd0b365427f4382e1332011-02-01T00:00:00Zhttps://mjps.nanotech.md/archive/2011/article/4300https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365MCD spectrum of the exchange coupled [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2] complex was analyzed. The analysis is based on the assumption that weak exchange interaction does not change the optical properties of the interacting ions and affects the saturation magnetization behavior only. The feature of MCD behavior, namely, the disappearance of some lines with increasing magnetic field and appearance again with the opposite sign, was explained by the overlap of the electronic transitions at different but near wavelengths. Ostrovschii, SergheiD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 10, Iss 1, Pp 26-32 (2011)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Ostrovschii, Serghei
Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
description MCD spectrum of the exchange coupled [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2] complex was analyzed. The analysis is based on the assumption that weak exchange interaction does not change the optical properties of the interacting ions and affects the saturation magnetization behavior only. The feature of MCD behavior, namely, the disappearance of some lines with increasing magnetic field and appearance again with the opposite sign, was explained by the overlap of the electronic transitions at different but near wavelengths.
format article
author Ostrovschii, Serghei
author_facet Ostrovschii, Serghei
author_sort Ostrovschii, Serghei
title Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
title_short Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
title_full Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
title_fullStr Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
title_full_unstemmed Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.
title_sort magnetic circular dichroism study of the exchange-coupled cobalt(ii) dimer.
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2011
url https://doaj.org/article/27439fbbdc844bd0b365427f4382e133
work_keys_str_mv AT ostrovschiiserghei magneticcirculardichroismstudyoftheexchangecoupledcobaltiidimer
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