Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure
Metal–organic frameworks that undergo structural transitions in response to external stimuli are promising for gas storage, but the mechanisms of such dynamics are poorly understood. Here the authors show that the structural transformation of ZIF-7 is induced by CO2 migration through its non-uniform...
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Nature Portfolio
2019
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oai:doaj.org-article:277231507c2540cd95517097e73146e82021-12-02T14:38:58ZStructural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure10.1038/s41467-019-08939-y2041-1723https://doaj.org/article/277231507c2540cd95517097e73146e82019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08939-yhttps://doaj.org/toc/2041-1723Metal–organic frameworks that undergo structural transitions in response to external stimuli are promising for gas storage, but the mechanisms of such dynamics are poorly understood. Here the authors show that the structural transformation of ZIF-7 is induced by CO2 migration through its non-uniform porous structure.Pu ZhaoHong FangSanghamitra MukhopadhyayAurelia LiSvemir RudićIan J. McPhersonChiu C. TangDavid Fairen-JimenezS. C. Edman TsangSimon A. T. RedfernNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019) |
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Science Q Pu Zhao Hong Fang Sanghamitra Mukhopadhyay Aurelia Li Svemir Rudić Ian J. McPherson Chiu C. Tang David Fairen-Jimenez S. C. Edman Tsang Simon A. T. Redfern Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure |
description |
Metal–organic frameworks that undergo structural transitions in response to external stimuli are promising for gas storage, but the mechanisms of such dynamics are poorly understood. Here the authors show that the structural transformation of ZIF-7 is induced by CO2 migration through its non-uniform porous structure. |
format |
article |
author |
Pu Zhao Hong Fang Sanghamitra Mukhopadhyay Aurelia Li Svemir Rudić Ian J. McPherson Chiu C. Tang David Fairen-Jimenez S. C. Edman Tsang Simon A. T. Redfern |
author_facet |
Pu Zhao Hong Fang Sanghamitra Mukhopadhyay Aurelia Li Svemir Rudić Ian J. McPherson Chiu C. Tang David Fairen-Jimenez S. C. Edman Tsang Simon A. T. Redfern |
author_sort |
Pu Zhao |
title |
Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure |
title_short |
Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure |
title_full |
Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure |
title_fullStr |
Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure |
title_full_unstemmed |
Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure |
title_sort |
structural dynamics of a metal–organic framework induced by co2 migration in its non-uniform porous structure |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/277231507c2540cd95517097e73146e8 |
work_keys_str_mv |
AT puzhao structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT hongfang structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT sanghamitramukhopadhyay structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT aureliali structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT svemirrudic structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT ianjmcpherson structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT chiuctang structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT davidfairenjimenez structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT scedmantsang structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure AT simonatredfern structuraldynamicsofametalorganicframeworkinducedbyco2migrationinitsnonuniformporousstructure |
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1718390761871900672 |