High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile
Chemical elements at high pressure may behave more consistently with their periodic properties than they do at ambient conditions. The authors report the synthesis of PH3 from black phosphorous and hydrogen, and the crystallization of the van der Waals compound (PH3)2H2 which fills a gap in the chem...
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Nature Portfolio
2020
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oai:doaj.org-article:279201f025c94439a590203efb6604bf2021-12-02T14:42:56ZHigh pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile10.1038/s41467-020-19745-22041-1723https://doaj.org/article/279201f025c94439a590203efb6604bf2020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19745-2https://doaj.org/toc/2041-1723Chemical elements at high pressure may behave more consistently with their periodic properties than they do at ambient conditions. The authors report the synthesis of PH3 from black phosphorous and hydrogen, and the crystallization of the van der Waals compound (PH3)2H2 which fills a gap in the chemistry of adjacent elements in the periodic table.Matteo CeppatelliDemetrio SceltaManuel Serrano-RuizKamil DziubekGaston GarbarinoJeroen JacobsMohamed MezouarRoberto BiniMaurizio PeruzziniNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020) |
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Science Q Matteo Ceppatelli Demetrio Scelta Manuel Serrano-Ruiz Kamil Dziubek Gaston Garbarino Jeroen Jacobs Mohamed Mezouar Roberto Bini Maurizio Peruzzini High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
description |
Chemical elements at high pressure may behave more consistently with their periodic properties than they do at ambient conditions. The authors report the synthesis of PH3 from black phosphorous and hydrogen, and the crystallization of the van der Waals compound (PH3)2H2 which fills a gap in the chemistry of adjacent elements in the periodic table. |
format |
article |
author |
Matteo Ceppatelli Demetrio Scelta Manuel Serrano-Ruiz Kamil Dziubek Gaston Garbarino Jeroen Jacobs Mohamed Mezouar Roberto Bini Maurizio Peruzzini |
author_facet |
Matteo Ceppatelli Demetrio Scelta Manuel Serrano-Ruiz Kamil Dziubek Gaston Garbarino Jeroen Jacobs Mohamed Mezouar Roberto Bini Maurizio Peruzzini |
author_sort |
Matteo Ceppatelli |
title |
High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
title_short |
High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
title_full |
High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
title_fullStr |
High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
title_full_unstemmed |
High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile |
title_sort |
high pressure synthesis of phosphine from the elements and the discovery of the missing (ph3)2h2 tile |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/279201f025c94439a590203efb6604bf |
work_keys_str_mv |
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1718389556348190720 |