Archean phosphorus liberation induced by iron redox geochemistry

Phosphorus is presumed to have been a limiting nutrient in the Archean ocean due to binding to iron oxides. Here, the authors show the heating of iron with phosphate results in the reduction of phosphate to the ion phosphite, which is solubilized and ameliorates the issue of a low Archean phosphorus...

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Auteurs principaux: Barry Herschy, Sae Jung Chang, Ruth Blake, Aivo Lepland, Heather Abbott-Lyon, Jacqueline Sampson, Zachary Atlas, Terence P. Kee, Matthew A. Pasek
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/27ab8d6fdeac4428aa1fbd4d7abd3014
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Résumé:Phosphorus is presumed to have been a limiting nutrient in the Archean ocean due to binding to iron oxides. Here, the authors show the heating of iron with phosphate results in the reduction of phosphate to the ion phosphite, which is solubilized and ameliorates the issue of a low Archean phosphorus supply.