The Effect of AlI3 Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique

Thermal degradation of polymethylmethacrylate (PMMA) was studied by using inorganic salt of aluminum triiodide (AlI3). The composites of PMMA were prepared with AlI3 by changing the concentration of the AlI3 additive from 2% to 10%...

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Autores principales:	Muhammad Adnan, Taj Ur Rahman, Ali Bahadur, Muhammad Aurang Zeb, Wajiha Liaqat, Takashiro Akitsu, Shams H. Abdel-Hafez, Wael A. El-Sayed
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	PMMA aluminum triiodide thermoanalytical study degradation Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Acceso en línea:	https://doaj.org/article/282d09c6111c48778e5450b6f426073e
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spelling	oai:doaj.org-article:282d09c6111c48778e5450b6f426073e2021-11-25T18:15:52ZThe Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique10.3390/ma142270361996-1944https://doaj.org/article/282d09c6111c48778e5450b6f426073e2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/7036https://doaj.org/toc/1996-1944Thermal degradation of polymethylmethacrylate (PMMA) was studied by using inorganic salt of aluminum triiodide (AlI<sub>3</sub>). The composites of PMMA were prepared with AlI<sub>3</sub> by changing the concentration of the AlI<sub>3</sub> additive from 2% to 10% (<i>w</i>/<i>w</i>). The PMMA composites with AlI<sub>3</sub> were characterized by TGA, DTG, SEM, FTIR, HBT, and Py-GC-MS techniques. The FTIR peaks of PMMA composite at 1316, 786, and 693 cm<sup>−1</sup> justify the chemical association between PMMA and AlI<sub>3</sub>. TGA study shows that the stability of PMMA is enhanced by the addition of the AlI<sub>3</sub> additive. SEM analysis represented that there is a relationship between polymer and additive when they are mixed at the molecular level. The horizontal burning test (HBT) also confirmed that the AlI<sub>3</sub> additive produced the flame retarding properties in PMMA polymer. The burning rate of composite with 10% of AlI<sub>3</sub> additive decreases five times as much as compared to pure PMMA polymer. Py-GC-MS analysis deduced that PMMA composite produced less toxic and environment-friendly substances (CO<sub>2</sub>) by the influence of AlI<sub>3</sub> additive as compared to neat PMMA.Muhammad AdnanTaj Ur RahmanAli BahadurMuhammad Aurang ZebWajiha LiaqatTakashiro AkitsuShams H. Abdel-HafezWael A. El-SayedMDPI AGarticlePMMAaluminum triiodidethermoanalytical studydegradationTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 7036, p 7036 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	PMMA aluminum triiodide thermoanalytical study degradation Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
spellingShingle	PMMA aluminum triiodide thermoanalytical study degradation Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Muhammad Adnan Taj Ur Rahman Ali Bahadur Muhammad Aurang Zeb Wajiha Liaqat Takashiro Akitsu Shams H. Abdel-Hafez Wael A. El-Sayed The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique
description	Thermal degradation of polymethylmethacrylate (PMMA) was studied by using inorganic salt of aluminum triiodide (AlI<sub>3</sub>). The composites of PMMA were prepared with AlI<sub>3</sub> by changing the concentration of the AlI<sub>3</sub> additive from 2% to 10% (<i>w</i>/<i>w</i>). The PMMA composites with AlI<sub>3</sub> were characterized by TGA, DTG, SEM, FTIR, HBT, and Py-GC-MS techniques. The FTIR peaks of PMMA composite at 1316, 786, and 693 cm<sup>−1</sup> justify the chemical association between PMMA and AlI<sub>3</sub>. TGA study shows that the stability of PMMA is enhanced by the addition of the AlI<sub>3</sub> additive. SEM analysis represented that there is a relationship between polymer and additive when they are mixed at the molecular level. The horizontal burning test (HBT) also confirmed that the AlI<sub>3</sub> additive produced the flame retarding properties in PMMA polymer. The burning rate of composite with 10% of AlI<sub>3</sub> additive decreases five times as much as compared to pure PMMA polymer. Py-GC-MS analysis deduced that PMMA composite produced less toxic and environment-friendly substances (CO<sub>2</sub>) by the influence of AlI<sub>3</sub> additive as compared to neat PMMA.
format	article
author	Muhammad Adnan Taj Ur Rahman Ali Bahadur Muhammad Aurang Zeb Wajiha Liaqat Takashiro Akitsu Shams H. Abdel-Hafez Wael A. El-Sayed
author_facet	Muhammad Adnan Taj Ur Rahman Ali Bahadur Muhammad Aurang Zeb Wajiha Liaqat Takashiro Akitsu Shams H. Abdel-Hafez Wael A. El-Sayed
author_sort	Muhammad Adnan
title	The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique
title_short	The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique
title_full	The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique
title_fullStr	The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique
title_full_unstemmed	The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique
title_sort	effect of ali<sub>3</sub> nanoadditive on the thermal behavior of pmma subjected to thermoanalytical py-gc-ms technique
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/282d09c6111c48778e5450b6f426073e
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The Effect of AlI<sub>3</sub> Nanoadditive on the Thermal Behavior of PMMA Subjected to Thermoanalytical Py-GC-MS Technique

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