Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters

Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalyst...

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Autores principales: Vicent Lloret, Miguel Ángel Rivero-Crespo, José Alejandro Vidal-Moya, Stefan Wild, Antonio Doménech-Carbó, Bettina S. J. Heller, Sunghwan Shin, Hans-Peter Steinrück, Florian Maier, Frank Hauke, Maria Varela, Andreas Hirsch, Antonio Leyva-Pérez, Gonzalo Abellán
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/28a596c09abf4115927d5c20f93f25ca
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spelling oai:doaj.org-article:28a596c09abf4115927d5c20f93f25ca2021-12-02T15:35:57ZFew layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters10.1038/s41467-018-08063-32041-1723https://doaj.org/article/28a596c09abf4115927d5c20f93f25ca2019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-08063-3https://doaj.org/toc/2041-1723Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters.Vicent LloretMiguel Ángel Rivero-CrespoJosé Alejandro Vidal-MoyaStefan WildAntonio Doménech-CarbóBettina S. J. HellerSunghwan ShinHans-Peter SteinrückFlorian MaierFrank HaukeMaria VarelaAndreas HirschAntonio Leyva-PérezGonzalo AbellánNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Vicent Lloret
Miguel Ángel Rivero-Crespo
José Alejandro Vidal-Moya
Stefan Wild
Antonio Doménech-Carbó
Bettina S. J. Heller
Sunghwan Shin
Hans-Peter Steinrück
Florian Maier
Frank Hauke
Maria Varela
Andreas Hirsch
Antonio Leyva-Pérez
Gonzalo Abellán
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
description Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters.
format article
author Vicent Lloret
Miguel Ángel Rivero-Crespo
José Alejandro Vidal-Moya
Stefan Wild
Antonio Doménech-Carbó
Bettina S. J. Heller
Sunghwan Shin
Hans-Peter Steinrück
Florian Maier
Frank Hauke
Maria Varela
Andreas Hirsch
Antonio Leyva-Pérez
Gonzalo Abellán
author_facet Vicent Lloret
Miguel Ángel Rivero-Crespo
José Alejandro Vidal-Moya
Stefan Wild
Antonio Doménech-Carbó
Bettina S. J. Heller
Sunghwan Shin
Hans-Peter Steinrück
Florian Maier
Frank Hauke
Maria Varela
Andreas Hirsch
Antonio Leyva-Pérez
Gonzalo Abellán
author_sort Vicent Lloret
title Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_short Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_full Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_fullStr Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_full_unstemmed Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_sort few layer 2d pnictogens catalyze the alkylation of soft nucleophiles with esters
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/28a596c09abf4115927d5c20f93f25ca
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