Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalyst...
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Nature Portfolio
2019
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oai:doaj.org-article:28a596c09abf4115927d5c20f93f25ca2021-12-02T15:35:57ZFew layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters10.1038/s41467-018-08063-32041-1723https://doaj.org/article/28a596c09abf4115927d5c20f93f25ca2019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-08063-3https://doaj.org/toc/2041-1723Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters.Vicent LloretMiguel Ángel Rivero-CrespoJosé Alejandro Vidal-MoyaStefan WildAntonio Doménech-CarbóBettina S. J. HellerSunghwan ShinHans-Peter SteinrückFlorian MaierFrank HaukeMaria VarelaAndreas HirschAntonio Leyva-PérezGonzalo AbellánNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019) |
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Science Q Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
description |
Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters. |
format |
article |
author |
Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán |
author_facet |
Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán |
author_sort |
Vicent Lloret |
title |
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
title_short |
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
title_full |
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
title_fullStr |
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
title_full_unstemmed |
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
title_sort |
few layer 2d pnictogens catalyze the alkylation of soft nucleophiles with esters |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/28a596c09abf4115927d5c20f93f25ca |
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