Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

High-valent iron compounds do not form spontaneously under ambient conditions and those that are synthetically available are rarely stable. Here, the authors synthesize stable iron(IV) hexahydrazide clathrochelate complexes in aqueous media via a metal-templated reaction accompanied by aerobic oxida...

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Autores principales:	Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/28c81f6d1be441e18e86efb166d46302
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spelling	oai:doaj.org-article:28c81f6d1be441e18e86efb166d463022021-12-02T14:40:22ZIndefinitely stable iron(IV) cage complexes formed in water by air oxidation10.1038/ncomms140992041-1723https://doaj.org/article/28c81f6d1be441e18e86efb166d463022017-01-01T00:00:00Zhttps://doi.org/10.1038/ncomms14099https://doaj.org/toc/2041-1723High-valent iron compounds do not form spontaneously under ambient conditions and those that are synthetically available are rarely stable. Here, the authors synthesize stable iron(IV) hexahydrazide clathrochelate complexes in aqueous media via a metal-templated reaction accompanied by aerobic oxidation.Stefania TomynSergii I. ShylinDmytro BykovVadim KsenofontovElzbieta Gumienna-KonteckaVolodymyr BonIgor O. FritskyNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Stefania Tomyn Sergii I. Shylin Dmytro Bykov Vadim Ksenofontov Elzbieta Gumienna-Kontecka Volodymyr Bon Igor O. Fritsky Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
description	High-valent iron compounds do not form spontaneously under ambient conditions and those that are synthetically available are rarely stable. Here, the authors synthesize stable iron(IV) hexahydrazide clathrochelate complexes in aqueous media via a metal-templated reaction accompanied by aerobic oxidation.
format	article
author	Stefania Tomyn Sergii I. Shylin Dmytro Bykov Vadim Ksenofontov Elzbieta Gumienna-Kontecka Volodymyr Bon Igor O. Fritsky
author_facet	Stefania Tomyn Sergii I. Shylin Dmytro Bykov Vadim Ksenofontov Elzbieta Gumienna-Kontecka Volodymyr Bon Igor O. Fritsky
author_sort	Stefania Tomyn
title	Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
title_short	Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
title_full	Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
title_fullStr	Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
title_full_unstemmed	Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
title_sort	indefinitely stable iron(iv) cage complexes formed in water by air oxidation
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/28c81f6d1be441e18e86efb166d46302
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_version_	1718390285008896000

Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

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