Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

High-valent iron compounds do not form spontaneously under ambient conditions and those that are synthetically available are rarely stable. Here, the authors synthesize stable iron(IV) hexahydrazide clathrochelate complexes in aqueous media via a metal-templated reaction accompanied by aerobic oxida...

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Autores principales: Stefania Tomyn, Sergii I. Shylin, Dmytro Bykov, Vadim Ksenofontov, Elzbieta Gumienna-Kontecka, Volodymyr Bon, Igor O. Fritsky
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/28c81f6d1be441e18e86efb166d46302
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