Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production

Heterogeneous catalysts are progressively expanding their field of application, from high-throughput reactions for traditional industrial chemistry with production volumes reaching millions of tons per year, a sector in which they are key players, to more niche applications for the production of fin...

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Autores principales:	Andrea Lazzarini, Roberta Colaiezzi, Francesco Gabriele, Marcello Crucianelli
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	structure–activity relationship single-atom catalysis green synthesis supported metals high-added value products Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Acceso en línea:	https://doaj.org/article/28dab930e56e4cad80541a8a26efa97a
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spelling	oai:doaj.org-article:28dab930e56e4cad80541a8a26efa97a2021-11-25T18:13:38ZSupport–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production10.3390/ma142267961996-1944https://doaj.org/article/28dab930e56e4cad80541a8a26efa97a2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/6796https://doaj.org/toc/1996-1944Heterogeneous catalysts are progressively expanding their field of application, from high-throughput reactions for traditional industrial chemistry with production volumes reaching millions of tons per year, a sector in which they are key players, to more niche applications for the production of fine chemicals. These novel applications require a progressive utilization reduction of fossil feedstocks, in favor of renewable ones. Biomasses are the most accessible source of organic precursors, having as advantage their low cost and even distribution across the globe. Unfortunately, they are intrinsically inhomogeneous in nature and their efficient exploitation requires novel catalysts. In this process, an accurate design of the active phase performing the reaction is important; nevertheless, we are often neglecting the importance of the support in guaranteeing stable performances and improving catalytic activity. This review has the goal of gathering and highlighting the cases in which the supports (either derived or not from biomass wastes) share the worth of performing the catalysis with the active phase, for those reactions involving the synthesis of fine chemicals starting from biomasses as feedstocks.Andrea LazzariniRoberta ColaiezziFrancesco GabrieleMarcello CrucianelliMDPI AGarticlestructure–activity relationshipsingle-atom catalysisgreen synthesissupported metalshigh-added value productsTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6796, p 6796 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	structure–activity relationship single-atom catalysis green synthesis supported metals high-added value products Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
spellingShingle	structure–activity relationship single-atom catalysis green synthesis supported metals high-added value products Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Andrea Lazzarini Roberta Colaiezzi Francesco Gabriele Marcello Crucianelli Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
description	Heterogeneous catalysts are progressively expanding their field of application, from high-throughput reactions for traditional industrial chemistry with production volumes reaching millions of tons per year, a sector in which they are key players, to more niche applications for the production of fine chemicals. These novel applications require a progressive utilization reduction of fossil feedstocks, in favor of renewable ones. Biomasses are the most accessible source of organic precursors, having as advantage their low cost and even distribution across the globe. Unfortunately, they are intrinsically inhomogeneous in nature and their efficient exploitation requires novel catalysts. In this process, an accurate design of the active phase performing the reaction is important; nevertheless, we are often neglecting the importance of the support in guaranteeing stable performances and improving catalytic activity. This review has the goal of gathering and highlighting the cases in which the supports (either derived or not from biomass wastes) share the worth of performing the catalysis with the active phase, for those reactions involving the synthesis of fine chemicals starting from biomasses as feedstocks.
format	article
author	Andrea Lazzarini Roberta Colaiezzi Francesco Gabriele Marcello Crucianelli
author_facet	Andrea Lazzarini Roberta Colaiezzi Francesco Gabriele Marcello Crucianelli
author_sort	Andrea Lazzarini
title	Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
title_short	Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
title_full	Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
title_fullStr	Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
title_full_unstemmed	Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production
title_sort	support–activity relationship in heterogeneous catalysis for biomass valorization and fine-chemicals production
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/28dab930e56e4cad80541a8a26efa97a
work_keys_str_mv	AT andrealazzarini supportactivityrelationshipinheterogeneouscatalysisforbiomassvalorizationandfinechemicalsproduction AT robertacolaiezzi supportactivityrelationshipinheterogeneouscatalysisforbiomassvalorizationandfinechemicalsproduction AT francescogabriele supportactivityrelationshipinheterogeneouscatalysisforbiomassvalorizationandfinechemicalsproduction AT marcellocrucianelli supportactivityrelationshipinheterogeneouscatalysisforbiomassvalorizationandfinechemicalsproduction
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Support–Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production

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