Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes

Graphitic oxide is readily produced by the oxidation of graphite. Here the authors show that the amount and nature of the oxidant can be used to tune the properties of graphitic oxide, and furthermore report a carbocatalyst for alkene epoxidation without the need for metal or initiators.

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Autores principales:	Samuel Pattisson, Ewa Nowicka, Upendra N. Gupta, Greg Shaw, Robert L. Jenkins, David J. Morgan, David W. Knight, Graham J. Hutchings
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/299352532e15440488a13ca6349c1edc
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spelling	oai:doaj.org-article:299352532e15440488a13ca6349c1edc2021-12-02T15:34:33ZTuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes10.1038/ncomms128552041-1723https://doaj.org/article/299352532e15440488a13ca6349c1edc2016-09-01T00:00:00Zhttps://doi.org/10.1038/ncomms12855https://doaj.org/toc/2041-1723Graphitic oxide is readily produced by the oxidation of graphite. Here the authors show that the amount and nature of the oxidant can be used to tune the properties of graphitic oxide, and furthermore report a carbocatalyst for alkene epoxidation without the need for metal or initiators.Samuel PattissonEwa NowickaUpendra N. GuptaGreg ShawRobert L. JenkinsDavid J. MorganDavid W. KnightGraham J. HutchingsNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-9 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Samuel Pattisson Ewa Nowicka Upendra N. Gupta Greg Shaw Robert L. Jenkins David J. Morgan David W. Knight Graham J. Hutchings Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
description	Graphitic oxide is readily produced by the oxidation of graphite. Here the authors show that the amount and nature of the oxidant can be used to tune the properties of graphitic oxide, and furthermore report a carbocatalyst for alkene epoxidation without the need for metal or initiators.
format	article
author	Samuel Pattisson Ewa Nowicka Upendra N. Gupta Greg Shaw Robert L. Jenkins David J. Morgan David W. Knight Graham J. Hutchings
author_facet	Samuel Pattisson Ewa Nowicka Upendra N. Gupta Greg Shaw Robert L. Jenkins David J. Morgan David W. Knight Graham J. Hutchings
author_sort	Samuel Pattisson
title	Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
title_short	Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
title_full	Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
title_fullStr	Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
title_full_unstemmed	Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
title_sort	tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/299352532e15440488a13ca6349c1edc
work_keys_str_mv	AT samuelpattisson tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT ewanowicka tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT upendrangupta tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT gregshaw tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT robertljenkins tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT davidjmorgan tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT davidwknight tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes AT grahamjhutchings tuninggraphiticoxideforinitiatorandmetalfreeaerobicepoxidationoflinearalkenes
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Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes

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