Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel

Abstract Hydrogen effect on semiconductivity and compositions of passive films formed on ferrite and austenite phases in a duplex stainless steel were investigated by current sensing atomic force microscopy and X-ray photoelectron spectroscopy. It is demonstrated that hydrogen significantly increase...

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Autores principales: L. Q. Guo, S. X. Qin, B. J. Yang, D. Liang, L. J. Qiao
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/2be844ba8b45489a85e15f10790f527e
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spelling oai:doaj.org-article:2be844ba8b45489a85e15f10790f527e2021-12-02T11:52:35ZEffect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel10.1038/s41598-017-03480-82045-2322https://doaj.org/article/2be844ba8b45489a85e15f10790f527e2017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-03480-8https://doaj.org/toc/2045-2322Abstract Hydrogen effect on semiconductivity and compositions of passive films formed on ferrite and austenite phases in a duplex stainless steel were investigated by current sensing atomic force microscopy and X-ray photoelectron spectroscopy. It is demonstrated that hydrogen significantly increases the conductivity of passive film due to the increase of OH−/O2− ratio. The passive film on austenite has higher conductivity than that on ferrite after hydrogen charging due to more hydrogen in austenite. The presence of hydrogen causes an inversion of conductivity type of passive film from p-type to n-type, attributed to the chemical composition change.L. Q. GuoS. X. QinB. J. YangD. LiangL. J. QiaoNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-6 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
L. Q. Guo
S. X. Qin
B. J. Yang
D. Liang
L. J. Qiao
Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
description Abstract Hydrogen effect on semiconductivity and compositions of passive films formed on ferrite and austenite phases in a duplex stainless steel were investigated by current sensing atomic force microscopy and X-ray photoelectron spectroscopy. It is demonstrated that hydrogen significantly increases the conductivity of passive film due to the increase of OH−/O2− ratio. The passive film on austenite has higher conductivity than that on ferrite after hydrogen charging due to more hydrogen in austenite. The presence of hydrogen causes an inversion of conductivity type of passive film from p-type to n-type, attributed to the chemical composition change.
format article
author L. Q. Guo
S. X. Qin
B. J. Yang
D. Liang
L. J. Qiao
author_facet L. Q. Guo
S. X. Qin
B. J. Yang
D. Liang
L. J. Qiao
author_sort L. Q. Guo
title Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
title_short Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
title_full Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
title_fullStr Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
title_full_unstemmed Effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
title_sort effect of hydrogen on semiconductive properties of passive film on ferrite and austenite phases in a duplex stainless steel
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/2be844ba8b45489a85e15f10790f527e
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