Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures

Abstract Electrochemiluminescence (ECL) refers to light emission induced by an electrochemical redox reaction. The stability, emission response, and light intensity of the ECL device are known to be improved by using an alternating current (AC) voltage. In this paper, an AC-driven ECL device is fabr...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Shota Tsuneyasu, Ryota Takahashi, Haruki Minami, Kazuki Nakamura, Norihisa Kobayashi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/2c1c3147b3ca457f8c462cff12ae48f8
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:2c1c3147b3ca457f8c462cff12ae48f8
record_format	dspace
spelling	oai:doaj.org-article:2c1c3147b3ca457f8c462cff12ae48f82021-12-02T12:30:36ZUltrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures10.1038/s41598-017-09123-22045-2322https://doaj.org/article/2c1c3147b3ca457f8c462cff12ae48f82017-08-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-09123-2https://doaj.org/toc/2045-2322Abstract Electrochemiluminescence (ECL) refers to light emission induced by an electrochemical redox reaction. The stability, emission response, and light intensity of the ECL device are known to be improved by using an alternating current (AC) voltage. In this paper, an AC-driven ECL device is fabricated with DNA/Ru(bpy)3 2+ hybrid film-modified electrode. The Ru(bpy)3 2+ complex exhibits significant electrochemical reactivity in the DNA/Ru(bpy)3 2+ hybrid film prepared by electrochemical adsorption. The hybrid film contains unique micrometre-scale aggregates of Ru(bpy)3 2+ in DNA matrix. The physicochemical properties of the hybrid film and its AC-driven ECL characteristics in the electrochemical device are studied. Orange-coloured ECL is observed to be emitted from only the aggregated structures in the hybrid film at the high AC frequency of 10 kHz, which corresponds to a response time shorter than 100 μs.Shota TsuneyasuRyota TakahashiHaruki MinamiKazuki NakamuraNorihisa KobayashiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Shota Tsuneyasu Ryota Takahashi Haruki Minami Kazuki Nakamura Norihisa Kobayashi Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures
description	Abstract Electrochemiluminescence (ECL) refers to light emission induced by an electrochemical redox reaction. The stability, emission response, and light intensity of the ECL device are known to be improved by using an alternating current (AC) voltage. In this paper, an AC-driven ECL device is fabricated with DNA/Ru(bpy)3 2+ hybrid film-modified electrode. The Ru(bpy)3 2+ complex exhibits significant electrochemical reactivity in the DNA/Ru(bpy)3 2+ hybrid film prepared by electrochemical adsorption. The hybrid film contains unique micrometre-scale aggregates of Ru(bpy)3 2+ in DNA matrix. The physicochemical properties of the hybrid film and its AC-driven ECL characteristics in the electrochemical device are studied. Orange-coloured ECL is observed to be emitted from only the aggregated structures in the hybrid film at the high AC frequency of 10 kHz, which corresponds to a response time shorter than 100 μs.
format	article
author	Shota Tsuneyasu Ryota Takahashi Haruki Minami Kazuki Nakamura Norihisa Kobayashi
author_facet	Shota Tsuneyasu Ryota Takahashi Haruki Minami Kazuki Nakamura Norihisa Kobayashi
author_sort	Shota Tsuneyasu
title	Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures
title_short	Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures
title_full	Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures
title_fullStr	Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures
title_full_unstemmed	Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures
title_sort	ultrafast response in ac-driven electrochemiluminescent cell using electrochemically active dna/ru(bpy)3 2+ hybrid film with mesoscopic structures
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/2c1c3147b3ca457f8c462cff12ae48f8
work_keys_str_mv	AT shotatsuneyasu ultrafastresponseinacdrivenelectrochemiluminescentcellusingelectrochemicallyactivednarubpy32hybridfilmwithmesoscopicstructures AT ryotatakahashi ultrafastresponseinacdrivenelectrochemiluminescentcellusingelectrochemicallyactivednarubpy32hybridfilmwithmesoscopicstructures AT harukiminami ultrafastresponseinacdrivenelectrochemiluminescentcellusingelectrochemicallyactivednarubpy32hybridfilmwithmesoscopicstructures AT kazukinakamura ultrafastresponseinacdrivenelectrochemiluminescentcellusingelectrochemicallyactivednarubpy32hybridfilmwithmesoscopicstructures AT norihisakobayashi ultrafastresponseinacdrivenelectrochemiluminescentcellusingelectrochemicallyactivednarubpy32hybridfilmwithmesoscopicstructures
_version_	1718394324834582528

Ultrafast Response in AC-Driven Electrochemiluminescent Cell Using Electrochemically Active DNA/Ru(bpy)3 2+ Hybrid Film with Mesoscopic Structures

Ejemplares similares