Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
Polymetalated aromatic compounds are challenging synthetic goals. Here, the authors describe the synthesis of tetra-aurated indole and octa-aurated benzodipyrrole complexes, in which incorporation of the aurated substituents at the nitrogen atoms leads to hyperconjugative aromaticity in the five-mem...
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2016
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/2cd472c8e27749f0a312d94db4a5f3c7 |
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| Sumario: | Polymetalated aromatic compounds are challenging synthetic goals. Here, the authors describe the synthesis of tetra-aurated indole and octa-aurated benzodipyrrole complexes, in which incorporation of the aurated substituents at the nitrogen atoms leads to hyperconjugative aromaticity in the five-membered rings. |
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