Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

Polymetalated aromatic compounds are challenging synthetic goals. Here, the authors describe the synthesis of tetra-aurated indole and octa-aurated benzodipyrrole complexes, in which incorporation of the aurated substituents at the nitrogen atoms leads to hyperconjugative aromaticity in the five-mem...

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Autores principales: Jun Yuan, Tingting Sun, Xin He, Ke An, Jun Zhu, Liang Zhao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/2cd472c8e27749f0a312d94db4a5f3c7
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spelling oai:doaj.org-article:2cd472c8e27749f0a312d94db4a5f3c72021-12-02T15:34:57ZSynthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums10.1038/ncomms114892041-1723https://doaj.org/article/2cd472c8e27749f0a312d94db4a5f3c72016-05-01T00:00:00Zhttps://doi.org/10.1038/ncomms11489https://doaj.org/toc/2041-1723Polymetalated aromatic compounds are challenging synthetic goals. Here, the authors describe the synthesis of tetra-aurated indole and octa-aurated benzodipyrrole complexes, in which incorporation of the aurated substituents at the nitrogen atoms leads to hyperconjugative aromaticity in the five-membered rings.Jun YuanTingting SunXin HeKe AnJun ZhuLiang ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jun Yuan
Tingting Sun
Xin He
Ke An
Jun Zhu
Liang Zhao
Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
description Polymetalated aromatic compounds are challenging synthetic goals. Here, the authors describe the synthesis of tetra-aurated indole and octa-aurated benzodipyrrole complexes, in which incorporation of the aurated substituents at the nitrogen atoms leads to hyperconjugative aromaticity in the five-membered rings.
format article
author Jun Yuan
Tingting Sun
Xin He
Ke An
Jun Zhu
Liang Zhao
author_facet Jun Yuan
Tingting Sun
Xin He
Ke An
Jun Zhu
Liang Zhao
author_sort Jun Yuan
title Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
title_short Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
title_full Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
title_fullStr Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
title_full_unstemmed Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
title_sort synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/2cd472c8e27749f0a312d94db4a5f3c7
work_keys_str_mv AT junyuan synthesisoftetraandoctaauratedheteroarylcomplexestowardsprobingaromaticindoliums
AT tingtingsun synthesisoftetraandoctaauratedheteroarylcomplexestowardsprobingaromaticindoliums
AT xinhe synthesisoftetraandoctaauratedheteroarylcomplexestowardsprobingaromaticindoliums
AT kean synthesisoftetraandoctaauratedheteroarylcomplexestowardsprobingaromaticindoliums
AT junzhu synthesisoftetraandoctaauratedheteroarylcomplexestowardsprobingaromaticindoliums
AT liangzhao synthesisoftetraandoctaauratedheteroarylcomplexestowardsprobingaromaticindoliums
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