The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes

Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coor...

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Autores principales:	Saiyed Tanzimjahan A., Adeyemi Jerry O., Onwudiwe Damian C.
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	zinc complexes nickel complexes dithiocarbamates coordination geometry biological application Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/2ce1ddaed507437d81307b9b76ce8966
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spelling	oai:doaj.org-article:2ce1ddaed507437d81307b9b76ce89662021-12-05T14:10:44ZThe structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes2391-542010.1515/chem-2021-0080https://doaj.org/article/2ce1ddaed507437d81307b9b76ce89662021-09-01T00:00:00Zhttps://doi.org/10.1515/chem-2021-0080https://doaj.org/toc/2391-5420Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coordination modes enhance the possibility for complex formation and make them useful in different areas especially in biomedical fields. A synergy exists in the metal ions and dithiocarbamate moieties, which tends to exert better properties than the respective individual components of the complex. These improved properties have also been attributed to the presence of the C–S bonds. Zinc and nickel ions have been majorly found to bind to the dithiocarbamate in bidentate modes, and consequently different geometries have resulted from this interaction. The aim of this review is to present some studies on the synthesis, structural chemistry, and the relevance of zinc and nickel dithiocarbamates complexes especially in biological systems.Saiyed Tanzimjahan A.Adeyemi Jerry O.Onwudiwe Damian C.De Gruyterarticlezinc complexesnickel complexesdithiocarbamatescoordination geometrybiological applicationChemistryQD1-999ENOpen Chemistry, Vol 19, Iss 1, Pp 974-986 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	zinc complexes nickel complexes dithiocarbamates coordination geometry biological application Chemistry QD1-999
spellingShingle	zinc complexes nickel complexes dithiocarbamates coordination geometry biological application Chemistry QD1-999 Saiyed Tanzimjahan A. Adeyemi Jerry O. Onwudiwe Damian C. The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
description	Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coordination modes enhance the possibility for complex formation and make them useful in different areas especially in biomedical fields. A synergy exists in the metal ions and dithiocarbamate moieties, which tends to exert better properties than the respective individual components of the complex. These improved properties have also been attributed to the presence of the C–S bonds. Zinc and nickel ions have been majorly found to bind to the dithiocarbamate in bidentate modes, and consequently different geometries have resulted from this interaction. The aim of this review is to present some studies on the synthesis, structural chemistry, and the relevance of zinc and nickel dithiocarbamates complexes especially in biological systems.
format	article
author	Saiyed Tanzimjahan A. Adeyemi Jerry O. Onwudiwe Damian C.
author_facet	Saiyed Tanzimjahan A. Adeyemi Jerry O. Onwudiwe Damian C.
author_sort	Saiyed Tanzimjahan A.
title	The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
title_short	The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
title_full	The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
title_fullStr	The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
title_full_unstemmed	The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
title_sort	structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/2ce1ddaed507437d81307b9b76ce8966
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The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes

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