Upcycling Waste Plastics into Multi-Walled Carbon Nanotube Composites via NiCo<sub>2</sub>O<sub>4</sub> Catalytic Pyrolysis
In this work, multi-walled carbon nanotube composites (MWCNCs) were produced by catalytic pyrolysis of post-consumer plastics with aluminium oxide-supported nickel, cobalt, and their bimetallic (Ni/α–Al<sub>2</sub>O<sub>3</sub>, Co/α–Al<sub>2</sub>O<sub>3<...
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| Autores principales: | , , , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
MDPI AG
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/2d8efaef614c49a29e34014a24c65241 |
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| Sumario: | In this work, multi-walled carbon nanotube composites (MWCNCs) were produced by catalytic pyrolysis of post-consumer plastics with aluminium oxide-supported nickel, cobalt, and their bimetallic (Ni/α–Al<sub>2</sub>O<sub>3</sub>, Co/α–Al<sub>2</sub>O<sub>3</sub>, and NiCo/α–Al<sub>2</sub>O<sub>3</sub>) oxide-based catalysts. The influence of catalyst composition and catalytic reaction temperature on the carbon yield and structure of CNCs were investigated. Different temperatures (800, 900, 950, and 1000 °C) and catalyst compositions (Ni, Co, and Ni/Co) were explored to maximize the yield of carbon deposited on the catalyst. The obtained results showed that at the same catalytic temperature (900 °C), a Ni/Co bimetallic catalyst exhibited higher carbon yield than the individual monometallic catalysts due to a better cracking capability on carbon-hydrogen bonds. With the increase of temperature, the carbon yield of the Ni/Co bimetallic catalyst increased first and then decreased. At a temperature of 950 °C, the Ni/Co bimetallic catalyst achieved its largest carbon yield, which can reach 255 mg g<sup>−1</sup><sub>plastic</sub>. The growth of CNCs followed a “particle-wire-tube” mechanism for all studied catalysts. This work finds the potential application of complex oxide composite material catalysts for the generation of CNCs in catalytic pyrolysis of wasted plastic. |
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