Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds

Selective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Here, the authors report that Zn2+ coordinated with N species on N-doped carbon catalysts can catalyze the aerobic oxidative cleavage and esterification of C(CO)-C...

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Autores principales:	Chao Xie, Longfei Lin, Liang Huang, Zixin Wang, Zhiwei Jiang, Zehui Zhang, Buxing Han
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2dd1a821edf24b8ba22b396262c2f43e
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spelling	oai:doaj.org-article:2dd1a821edf24b8ba22b396262c2f43e2021-12-02T16:28:52ZZn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds10.1038/s41467-021-25118-02041-1723https://doaj.org/article/2dd1a821edf24b8ba22b396262c2f43e2021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25118-0https://doaj.org/toc/2041-1723Selective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Here, the authors report that Zn2+ coordinated with N species on N-doped carbon catalysts can catalyze the aerobic oxidative cleavage and esterification of C(CO)-C bonds with high efficiency and activity.Chao XieLongfei LinLiang HuangZixin WangZhiwei JiangZehui ZhangBuxing HanNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-12 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chao Xie Longfei Lin Liang Huang Zixin Wang Zhiwei Jiang Zehui Zhang Buxing Han Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
description	Selective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Here, the authors report that Zn2+ coordinated with N species on N-doped carbon catalysts can catalyze the aerobic oxidative cleavage and esterification of C(CO)-C bonds with high efficiency and activity.
format	article
author	Chao Xie Longfei Lin Liang Huang Zixin Wang Zhiwei Jiang Zehui Zhang Buxing Han
author_facet	Chao Xie Longfei Lin Liang Huang Zixin Wang Zhiwei Jiang Zehui Zhang Buxing Han
author_sort	Chao Xie
title	Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
title_short	Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
title_full	Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
title_fullStr	Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
title_full_unstemmed	Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
title_sort	zn-nx sites on n-doped carbon for aerobic oxidative cleavage and esterification of c(co)-c bonds
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/2dd1a821edf24b8ba22b396262c2f43e
work_keys_str_mv	AT chaoxie znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT longfeilin znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT lianghuang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT zixinwang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT zhiweijiang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT zehuizhang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT buxinghan znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds
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Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds

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