Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidan...
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Nature Portfolio
2017
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oai:doaj.org-article:2e18733cf7704f7abc21025d655479752021-12-02T14:41:20ZPhoto-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid10.1038/ncomms143532041-1723https://doaj.org/article/2e18733cf7704f7abc21025d655479752017-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms14353https://doaj.org/toc/2041-1723C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant.Jin LinZhi LiJian KanShijun HuangWeiping SuYadong LiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Jin Lin Zhi Li Jian Kan Shijun Huang Weiping Su Yadong Li Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
description |
C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant. |
format |
article |
author |
Jin Lin Zhi Li Jian Kan Shijun Huang Weiping Su Yadong Li |
author_facet |
Jin Lin Zhi Li Jian Kan Shijun Huang Weiping Su Yadong Li |
author_sort |
Jin Lin |
title |
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
title_short |
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
title_full |
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
title_fullStr |
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
title_full_unstemmed |
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
title_sort |
photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/2e18733cf7704f7abc21025d65547975 |
work_keys_str_mv |
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_version_ |
1718389920433700864 |