Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid

C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidan...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Jin Lin, Zhi Li, Jian Kan, Shijun Huang, Weiping Su, Yadong Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
Materias:
Q
Acceso en línea:https://doaj.org/article/2e18733cf7704f7abc21025d65547975
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:2e18733cf7704f7abc21025d65547975
record_format dspace
spelling oai:doaj.org-article:2e18733cf7704f7abc21025d655479752021-12-02T14:41:20ZPhoto-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid10.1038/ncomms143532041-1723https://doaj.org/article/2e18733cf7704f7abc21025d655479752017-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms14353https://doaj.org/toc/2041-1723C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant.Jin LinZhi LiJian KanShijun HuangWeiping SuYadong LiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jin Lin
Zhi Li
Jian Kan
Shijun Huang
Weiping Su
Yadong Li
Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
description C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant.
format article
author Jin Lin
Zhi Li
Jian Kan
Shijun Huang
Weiping Su
Yadong Li
author_facet Jin Lin
Zhi Li
Jian Kan
Shijun Huang
Weiping Su
Yadong Li
author_sort Jin Lin
title Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_short Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_full Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_fullStr Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_full_unstemmed Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
title_sort photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/2e18733cf7704f7abc21025d65547975
work_keys_str_mv AT jinlin photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT zhili photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT jiankan photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT shijunhuang photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT weipingsu photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
AT yadongli photodrivenredoxneutraldecarboxylativecarbonhydrogentrifluoromethylationofheteroareneswithtrifluoroaceticacid
_version_ 1718389920433700864