Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion
The application of bio-based materials is becoming impellent owing to the increasing demand for alternatives to petroleum-based analogs. In this regard, cellulose nanocrystals (CNCs) with unique properties have received a significant interest, while their hydrophilic character poses a challenge to t...
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2020
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oai:doaj.org-article:2e3f3378046c4fc493a0a10e5c16f0022021-12-02T12:35:26ZSonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion2055-033210.1080/20550324.2019.1710974https://doaj.org/article/2e3f3378046c4fc493a0a10e5c16f0022020-01-01T00:00:00Zhttp://dx.doi.org/10.1080/20550324.2019.1710974https://doaj.org/toc/2055-0332The application of bio-based materials is becoming impellent owing to the increasing demand for alternatives to petroleum-based analogs. In this regard, cellulose nanocrystals (CNCs) with unique properties have received a significant interest, while their hydrophilic character poses a challenge to their commercial applications. Ultrasonication treatment is one of the most commonly used methods to improve CNCs’ dispersion in different solvents and polymer matrices. In this work, the effectiveness of ultrasonication treatment in the dispersion of CNCs in a water-soluble polymer (polyvinyl alcohol, PVA) was studied. An aqueous suspension of polyvinyl alcohol and CNCs was prepared using different ultrasonication times and amplitudes. The morphology, particle size and dispersion of CNCs were studied using X-ray diffraction, transmission electron microscopy, and dynamic light scattering. The results indicated that with increase in the sonication amplitude, there was a substantial decrease in nanoparticle length, while long sonication times gently affected the nanoparticle length. Furthermore, improved dispersion was observed in samples prepared using longer sonication time.Jamileh ShojaeiaraniDilpreet BajwaGreg HoltTaylor & Francis Grouparticlesonication amplitudesonication timecellulose nanocrystalsdispersionparticle sizeMaterials of engineering and construction. Mechanics of materialsTA401-492Polymers and polymer manufactureTP1080-1185ENNanocomposites, Vol 6, Iss 1, Pp 41-46 (2020) |
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sonication amplitude sonication time cellulose nanocrystals dispersion particle size Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185 |
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sonication amplitude sonication time cellulose nanocrystals dispersion particle size Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185 Jamileh Shojaeiarani Dilpreet Bajwa Greg Holt Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
description |
The application of bio-based materials is becoming impellent owing to the increasing demand for alternatives to petroleum-based analogs. In this regard, cellulose nanocrystals (CNCs) with unique properties have received a significant interest, while their hydrophilic character poses a challenge to their commercial applications. Ultrasonication treatment is one of the most commonly used methods to improve CNCs’ dispersion in different solvents and polymer matrices. In this work, the effectiveness of ultrasonication treatment in the dispersion of CNCs in a water-soluble polymer (polyvinyl alcohol, PVA) was studied. An aqueous suspension of polyvinyl alcohol and CNCs was prepared using different ultrasonication times and amplitudes. The morphology, particle size and dispersion of CNCs were studied using X-ray diffraction, transmission electron microscopy, and dynamic light scattering. The results indicated that with increase in the sonication amplitude, there was a substantial decrease in nanoparticle length, while long sonication times gently affected the nanoparticle length. Furthermore, improved dispersion was observed in samples prepared using longer sonication time. |
format |
article |
author |
Jamileh Shojaeiarani Dilpreet Bajwa Greg Holt |
author_facet |
Jamileh Shojaeiarani Dilpreet Bajwa Greg Holt |
author_sort |
Jamileh Shojaeiarani |
title |
Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
title_short |
Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
title_full |
Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
title_fullStr |
Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
title_full_unstemmed |
Sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
title_sort |
sonication amplitude and processing time influence the cellulose nanocrystals morphology and dispersion |
publisher |
Taylor & Francis Group |
publishDate |
2020 |
url |
https://doaj.org/article/2e3f3378046c4fc493a0a10e5c16f002 |
work_keys_str_mv |
AT jamilehshojaeiarani sonicationamplitudeandprocessingtimeinfluencethecellulosenanocrystalsmorphologyanddispersion AT dilpreetbajwa sonicationamplitudeandprocessingtimeinfluencethecellulosenanocrystalsmorphologyanddispersion AT gregholt sonicationamplitudeandprocessingtimeinfluencethecellulosenanocrystalsmorphologyanddispersion |
_version_ |
1718393790807408640 |