Photoredox-catalyzed oxo-amination of aryl cyclopropanes

The ring-opening and functionalization of electronically unbiased cyclopropanes is highly challenging to achieve in a regioselective fashion. Here, the authors report a mild photoredox-coupled oxoamination of electronically unactivated aryl cyclopropanes with simple azaarenes and molecular oxygen.

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Detalles Bibliográficos
Autores principales: Liang Ge, Ding-Xing Wang, Renyi Xing, Di Ma, Patrick J. Walsh, Chao Feng
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/2e9963e7c7d24a2bb5c15475794ae524
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Descripción
Sumario:The ring-opening and functionalization of electronically unbiased cyclopropanes is highly challenging to achieve in a regioselective fashion. Here, the authors report a mild photoredox-coupled oxoamination of electronically unactivated aryl cyclopropanes with simple azaarenes and molecular oxygen.