Photoredox-catalyzed oxo-amination of aryl cyclopropanes

The ring-opening and functionalization of electronically unbiased cyclopropanes is highly challenging to achieve in a regioselective fashion. Here, the authors report a mild photoredox-coupled oxoamination of electronically unactivated aryl cyclopropanes with simple azaarenes and molecular oxygen.

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Autores principales:	Liang Ge, Ding-Xing Wang, Renyi Xing, Di Ma, Patrick J. Walsh, Chao Feng
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2e9963e7c7d24a2bb5c15475794ae524
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spelling	oai:doaj.org-article:2e9963e7c7d24a2bb5c15475794ae5242021-12-02T15:35:32ZPhotoredox-catalyzed oxo-amination of aryl cyclopropanes10.1038/s41467-019-12403-22041-1723https://doaj.org/article/2e9963e7c7d24a2bb5c15475794ae5242019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12403-2https://doaj.org/toc/2041-1723The ring-opening and functionalization of electronically unbiased cyclopropanes is highly challenging to achieve in a regioselective fashion. Here, the authors report a mild photoredox-coupled oxoamination of electronically unactivated aryl cyclopropanes with simple azaarenes and molecular oxygen.Liang GeDing-Xing WangRenyi XingDi MaPatrick J. WalshChao FengNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Liang Ge Ding-Xing Wang Renyi Xing Di Ma Patrick J. Walsh Chao Feng Photoredox-catalyzed oxo-amination of aryl cyclopropanes
description	The ring-opening and functionalization of electronically unbiased cyclopropanes is highly challenging to achieve in a regioselective fashion. Here, the authors report a mild photoredox-coupled oxoamination of electronically unactivated aryl cyclopropanes with simple azaarenes and molecular oxygen.
format	article
author	Liang Ge Ding-Xing Wang Renyi Xing Di Ma Patrick J. Walsh Chao Feng
author_facet	Liang Ge Ding-Xing Wang Renyi Xing Di Ma Patrick J. Walsh Chao Feng
author_sort	Liang Ge
title	Photoredox-catalyzed oxo-amination of aryl cyclopropanes
title_short	Photoredox-catalyzed oxo-amination of aryl cyclopropanes
title_full	Photoredox-catalyzed oxo-amination of aryl cyclopropanes
title_fullStr	Photoredox-catalyzed oxo-amination of aryl cyclopropanes
title_full_unstemmed	Photoredox-catalyzed oxo-amination of aryl cyclopropanes
title_sort	photoredox-catalyzed oxo-amination of aryl cyclopropanes
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/2e9963e7c7d24a2bb5c15475794ae524
work_keys_str_mv	AT liangge photoredoxcatalyzedoxoaminationofarylcyclopropanes AT dingxingwang photoredoxcatalyzedoxoaminationofarylcyclopropanes AT renyixing photoredoxcatalyzedoxoaminationofarylcyclopropanes AT dima photoredoxcatalyzedoxoaminationofarylcyclopropanes AT patrickjwalsh photoredoxcatalyzedoxoaminationofarylcyclopropanes AT chaofeng photoredoxcatalyzedoxoaminationofarylcyclopropanes
_version_	1718386523556020224

Photoredox-catalyzed oxo-amination of aryl cyclopropanes

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