Mechanical gating of a mechanochemical reaction cascade

Polymer mechanochemistry offers opportunities to control and engineer desired chemical transformations. Here, Craig and co-workers present a mechanical gating system whereby one mechanophore modulates the reactivity of another, resulting in a mechanochemical cascade reaction.

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Detalles Bibliográficos
Autores principales: Junpeng Wang, Tatiana B. Kouznetsova, Roman Boulatov, Stephen L. Craig
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/2ee6aef122ab46d38cd3f3f3723469fe
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Descripción
Sumario:Polymer mechanochemistry offers opportunities to control and engineer desired chemical transformations. Here, Craig and co-workers present a mechanical gating system whereby one mechanophore modulates the reactivity of another, resulting in a mechanochemical cascade reaction.