Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands

Crystalline materials that undergo large structural changes in response to external stimuli remain rare. Here the authors report a Zinc(II) complex that undergoes a two-step reversible single-crystal-to-single-crystal transformation via thermal removal of ethylene glycol chelating ligands; this resu...

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Autores principales:	Yun Li, Bo Zhao, Jin-Peng Xue, Jing Xie, Zi-Shuo Yao, Jun Tao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/2f9f854f0650447fb4c33f8115f076c0
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spelling	oai:doaj.org-article:2f9f854f0650447fb4c33f8115f076c02021-11-28T12:33:39ZGiant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands10.1038/s41467-021-27282-92041-1723https://doaj.org/article/2f9f854f0650447fb4c33f8115f076c02021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-27282-9https://doaj.org/toc/2041-1723Crystalline materials that undergo large structural changes in response to external stimuli remain rare. Here the authors report a Zinc(II) complex that undergoes a two-step reversible single-crystal-to-single-crystal transformation via thermal removal of ethylene glycol chelating ligands; this results in large volume changes.Yun LiBo ZhaoJin-Peng XueJing XieZi-Shuo YaoJun TaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yun Li Bo Zhao Jin-Peng Xue Jing Xie Zi-Shuo Yao Jun Tao Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
description	Crystalline materials that undergo large structural changes in response to external stimuli remain rare. Here the authors report a Zinc(II) complex that undergoes a two-step reversible single-crystal-to-single-crystal transformation via thermal removal of ethylene glycol chelating ligands; this results in large volume changes.
format	article
author	Yun Li Bo Zhao Jin-Peng Xue Jing Xie Zi-Shuo Yao Jun Tao
author_facet	Yun Li Bo Zhao Jin-Peng Xue Jing Xie Zi-Shuo Yao Jun Tao
author_sort	Yun Li
title	Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
title_short	Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
title_full	Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
title_fullStr	Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
title_full_unstemmed	Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
title_sort	giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/2f9f854f0650447fb4c33f8115f076c0
work_keys_str_mv	AT yunli giantsinglecrystaltosinglecrystaltransformationsassociatedwithchiralinterconversioninducedbyeliminationofchelatingligands AT bozhao giantsinglecrystaltosinglecrystaltransformationsassociatedwithchiralinterconversioninducedbyeliminationofchelatingligands AT jinpengxue giantsinglecrystaltosinglecrystaltransformationsassociatedwithchiralinterconversioninducedbyeliminationofchelatingligands AT jingxie giantsinglecrystaltosinglecrystaltransformationsassociatedwithchiralinterconversioninducedbyeliminationofchelatingligands AT zishuoyao giantsinglecrystaltosinglecrystaltransformationsassociatedwithchiralinterconversioninducedbyeliminationofchelatingligands AT juntao giantsinglecrystaltosinglecrystaltransformationsassociatedwithchiralinterconversioninducedbyeliminationofchelatingligands
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Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands

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