Development of a robust method for the determination of fluorine in liquid petroleum products

A robust method for the determination of total fluorine in liquid petroleum products is developed. The methodology is based on the oxidative pyrohydrolytic combustion of the sample, followed by the analysis of the evolved gases absorbed in an absorbing solution by ion chromatography. The detection l...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	María Fernanda Gazulla, Marta Rodrigo, María Jesús Ventura, Cristina Andreu, Mónica Orduña
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Fluorine Fuel oil Oxidative pyrohydrolitic combustion Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/2fb10767cf504d90b85265e538f7490d
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:2fb10767cf504d90b85265e538f7490d
record_format	dspace
spelling	oai:doaj.org-article:2fb10767cf504d90b85265e538f7490d2021-11-12T04:32:21ZDevelopment of a robust method for the determination of fluorine in liquid petroleum products2211-715610.1016/j.rechem.2021.100235https://doaj.org/article/2fb10767cf504d90b85265e538f7490d2021-01-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2211715621001405https://doaj.org/toc/2211-7156A robust method for the determination of total fluorine in liquid petroleum products is developed. The methodology is based on the oxidative pyrohydrolytic combustion of the sample, followed by the analysis of the evolved gases absorbed in an absorbing solution by ion chromatography. The detection limit reached for fluorine is 0.5 mg·kg−1 and the quantification limit is 1.4 mg·kg−1, thanks to the optimisation of different variables: combustion variables (temperature and time), sampling loop, and sample weight. The validation process has been developed by calculation of the uncertainty of the measurement and the analysis of spiked samples as there are no certified reference materials. The new methodology set up permits the determination of fluorine over organic materials from the refining industry of different matrices such as fuel oil, acid soluble oil, etc., containing from very low to high fluorine concentrations in a relatively short time, which makes the methodology suitable to be used as a control method. With this methodology, there is no need of sample preparation which implies the no use of acids for that, thus being environmentally friendly.María Fernanda GazullaMarta RodrigoMaría Jesús VenturaCristina AndreuMónica OrduñaElsevierarticleFluorineFuel oilOxidative pyrohydrolitic combustionChemistryQD1-999ENResults in Chemistry, Vol 3, Iss , Pp 100235- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Fluorine Fuel oil Oxidative pyrohydrolitic combustion Chemistry QD1-999
spellingShingle	Fluorine Fuel oil Oxidative pyrohydrolitic combustion Chemistry QD1-999 María Fernanda Gazulla Marta Rodrigo María Jesús Ventura Cristina Andreu Mónica Orduña Development of a robust method for the determination of fluorine in liquid petroleum products
description	A robust method for the determination of total fluorine in liquid petroleum products is developed. The methodology is based on the oxidative pyrohydrolytic combustion of the sample, followed by the analysis of the evolved gases absorbed in an absorbing solution by ion chromatography. The detection limit reached for fluorine is 0.5 mg·kg−1 and the quantification limit is 1.4 mg·kg−1, thanks to the optimisation of different variables: combustion variables (temperature and time), sampling loop, and sample weight. The validation process has been developed by calculation of the uncertainty of the measurement and the analysis of spiked samples as there are no certified reference materials. The new methodology set up permits the determination of fluorine over organic materials from the refining industry of different matrices such as fuel oil, acid soluble oil, etc., containing from very low to high fluorine concentrations in a relatively short time, which makes the methodology suitable to be used as a control method. With this methodology, there is no need of sample preparation which implies the no use of acids for that, thus being environmentally friendly.
format	article
author	María Fernanda Gazulla Marta Rodrigo María Jesús Ventura Cristina Andreu Mónica Orduña
author_facet	María Fernanda Gazulla Marta Rodrigo María Jesús Ventura Cristina Andreu Mónica Orduña
author_sort	María Fernanda Gazulla
title	Development of a robust method for the determination of fluorine in liquid petroleum products
title_short	Development of a robust method for the determination of fluorine in liquid petroleum products
title_full	Development of a robust method for the determination of fluorine in liquid petroleum products
title_fullStr	Development of a robust method for the determination of fluorine in liquid petroleum products
title_full_unstemmed	Development of a robust method for the determination of fluorine in liquid petroleum products
title_sort	development of a robust method for the determination of fluorine in liquid petroleum products
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/2fb10767cf504d90b85265e538f7490d
work_keys_str_mv	AT mariafernandagazulla developmentofarobustmethodforthedeterminationoffluorineinliquidpetroleumproducts AT martarodrigo developmentofarobustmethodforthedeterminationoffluorineinliquidpetroleumproducts AT mariajesusventura developmentofarobustmethodforthedeterminationoffluorineinliquidpetroleumproducts AT cristinaandreu developmentofarobustmethodforthedeterminationoffluorineinliquidpetroleumproducts AT monicaorduna developmentofarobustmethodforthedeterminationoffluorineinliquidpetroleumproducts
_version_	1718431281594761216

Development of a robust method for the determination of fluorine in liquid petroleum products

Ejemplares similares