Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry

Cross-coupling reactions have been achieved in solution, yet tend to be inefficient in a solid state. Here, the authors report a solid-state palladium-catalyzed Buchwald-Hartwig cross-coupling using olefins as molecular dispersants, enabling reduction of solvent waste.

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Autores principales:	Koji Kubota, Tamae Seo, Katsumasa Koide, Yasuchika Hasegawa, Hajime Ito
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/31051c40db434e458b8cdf204a3484c0
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spelling	oai:doaj.org-article:31051c40db434e458b8cdf204a3484c02021-12-02T15:36:23ZOlefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry10.1038/s41467-018-08017-92041-1723https://doaj.org/article/31051c40db434e458b8cdf204a3484c02019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-08017-9https://doaj.org/toc/2041-1723Cross-coupling reactions have been achieved in solution, yet tend to be inefficient in a solid state. Here, the authors report a solid-state palladium-catalyzed Buchwald-Hartwig cross-coupling using olefins as molecular dispersants, enabling reduction of solvent waste.Koji KubotaTamae SeoKatsumasa KoideYasuchika HasegawaHajime ItoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Koji Kubota Tamae Seo Katsumasa Koide Yasuchika Hasegawa Hajime Ito Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
description	Cross-coupling reactions have been achieved in solution, yet tend to be inefficient in a solid state. Here, the authors report a solid-state palladium-catalyzed Buchwald-Hartwig cross-coupling using olefins as molecular dispersants, enabling reduction of solvent waste.
format	article
author	Koji Kubota Tamae Seo Katsumasa Koide Yasuchika Hasegawa Hajime Ito
author_facet	Koji Kubota Tamae Seo Katsumasa Koide Yasuchika Hasegawa Hajime Ito
author_sort	Koji Kubota
title	Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
title_short	Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
title_full	Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
title_fullStr	Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
title_full_unstemmed	Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
title_sort	olefin-accelerated solid-state c–n cross-coupling reactions using mechanochemistry
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/31051c40db434e458b8cdf204a3484c0
work_keys_str_mv	AT kojikubota olefinacceleratedsolidstatecncrosscouplingreactionsusingmechanochemistry AT tamaeseo olefinacceleratedsolidstatecncrosscouplingreactionsusingmechanochemistry AT katsumasakoide olefinacceleratedsolidstatecncrosscouplingreactionsusingmechanochemistry AT yasuchikahasegawa olefinacceleratedsolidstatecncrosscouplingreactionsusingmechanochemistry AT hajimeito olefinacceleratedsolidstatecncrosscouplingreactionsusingmechanochemistry
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Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry

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