Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature

In this study, activated carbon fibers (ACFs) were prepared using a new method from polyethylene (PE) fibers. The stabilizing (or crosslinking) process of PE, an essential step, was achieved through a hybrid treatment using electron-beam/sulfuric acid at 110 °C that was more effective than the tradi...

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Autores principales: Kwan-Woo Kim, Hye-Min Lee, Seong-Hyun Kang, Byung-Joo Kim
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/31f6bc537d48470bb555feeabcdbf241
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spelling oai:doaj.org-article:31f6bc537d48470bb555feeabcdbf2412021-11-25T18:48:18ZSynthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature10.3390/polym132239182073-4360https://doaj.org/article/31f6bc537d48470bb555feeabcdbf2412021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3918https://doaj.org/toc/2073-4360In this study, activated carbon fibers (ACFs) were prepared using a new method from polyethylene (PE) fibers. The stabilizing (or crosslinking) process of PE, an essential step, was achieved through a hybrid treatment using electron-beam/sulfuric acid at 110 °C that was more effective than the traditional method of using sulfuric acid at 180 °C for polyolefin. The stabilized precursor was then carbonized at 700 °C and activated at 900 °C with different activation times. The structural characteristics and morphologies of these ACFs were observed using an X-ray diffractometer and a field-emission scanning electron microscope, respectively. In addition, the N<sub>2</sub>/77K adsorption isotherm was used to discern textural properties. The total pore volume and specific surface area of these ACFs were found to be increased with a longer activation time, reaching final values of 0.99 cm<sup>3</sup>/g and 1750 m<sup>2</sup>/g, respectively. These ACFs also exhibited a high mesopore volume ratio (39%) according to crosslinking and crystallite formation conditions.Kwan-Woo KimHye-Min LeeSeong-Hyun KangByung-Joo KimMDPI AGarticlecarbon fibersrecyclingupcyclingrecoverycarbon fibers reinforced plasticsOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3918, p 3918 (2021)
institution DOAJ
collection DOAJ
language EN
topic carbon fibers
recycling
upcycling
recovery
carbon fibers reinforced plastics
Organic chemistry
QD241-441
spellingShingle carbon fibers
recycling
upcycling
recovery
carbon fibers reinforced plastics
Organic chemistry
QD241-441
Kwan-Woo Kim
Hye-Min Lee
Seong-Hyun Kang
Byung-Joo Kim
Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature
description In this study, activated carbon fibers (ACFs) were prepared using a new method from polyethylene (PE) fibers. The stabilizing (or crosslinking) process of PE, an essential step, was achieved through a hybrid treatment using electron-beam/sulfuric acid at 110 °C that was more effective than the traditional method of using sulfuric acid at 180 °C for polyolefin. The stabilized precursor was then carbonized at 700 °C and activated at 900 °C with different activation times. The structural characteristics and morphologies of these ACFs were observed using an X-ray diffractometer and a field-emission scanning electron microscope, respectively. In addition, the N<sub>2</sub>/77K adsorption isotherm was used to discern textural properties. The total pore volume and specific surface area of these ACFs were found to be increased with a longer activation time, reaching final values of 0.99 cm<sup>3</sup>/g and 1750 m<sup>2</sup>/g, respectively. These ACFs also exhibited a high mesopore volume ratio (39%) according to crosslinking and crystallite formation conditions.
format article
author Kwan-Woo Kim
Hye-Min Lee
Seong-Hyun Kang
Byung-Joo Kim
author_facet Kwan-Woo Kim
Hye-Min Lee
Seong-Hyun Kang
Byung-Joo Kim
author_sort Kwan-Woo Kim
title Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature
title_short Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature
title_full Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature
title_fullStr Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature
title_full_unstemmed Synthesis and Characterization of Activated Carbon Fibers Derived from Linear Low-Density Polyethylene Fibers Stabilized at a Low Temperature
title_sort synthesis and characterization of activated carbon fibers derived from linear low-density polyethylene fibers stabilized at a low temperature
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/31f6bc537d48470bb555feeabcdbf241
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AT seonghyunkang synthesisandcharacterizationofactivatedcarbonfibersderivedfromlinearlowdensitypolyethylenefibersstabilizedatalowtemperature
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