Facilitating nitrogen accessibility to boron-rich covalent organic frameworks via electrochemical excitation for efficient nitrogen fixation

Covalent organic frameworks are potential catalysts for nitrogen reduction, but limited nitrogen transport restricts the utilization ratio of active sites. Here, the authors demonstrate that electrochemical excitation of covalent organic frameworks can lead to efficient nitrogen reduction.

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Detalles Bibliográficos
Autores principales: Sisi Liu, Mengfan Wang, Tao Qian, Haoqing Ji, Jie Liu, Chenglin Yan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/329a6ccd62704c6a8c93d06d40f89d82
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Descripción
Sumario:Covalent organic frameworks are potential catalysts for nitrogen reduction, but limited nitrogen transport restricts the utilization ratio of active sites. Here, the authors demonstrate that electrochemical excitation of covalent organic frameworks can lead to efficient nitrogen reduction.