Facilitating nitrogen accessibility to boron-rich covalent organic frameworks via electrochemical excitation for efficient nitrogen fixation

Covalent organic frameworks are potential catalysts for nitrogen reduction, but limited nitrogen transport restricts the utilization ratio of active sites. Here, the authors demonstrate that electrochemical excitation of covalent organic frameworks can lead to efficient nitrogen reduction.

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Auteurs principaux: Sisi Liu, Mengfan Wang, Tao Qian, Haoqing Ji, Jie Liu, Chenglin Yan
Format: article
Langue:EN
Publié: Nature Portfolio 2019
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Accès en ligne:https://doaj.org/article/329a6ccd62704c6a8c93d06d40f89d82
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Résumé:Covalent organic frameworks are potential catalysts for nitrogen reduction, but limited nitrogen transport restricts the utilization ratio of active sites. Here, the authors demonstrate that electrochemical excitation of covalent organic frameworks can lead to efficient nitrogen reduction.