Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy

Solid-state NMR can in principle be used to study calcium environments in biomaterials such as bones/teeth, but43Ca lacks receptivity. Here the authors present an approach to acquire 43Ca data for hydroxyapatite at its natural isotopic abundance, distinguishing between core and surface Ca sites.

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Autores principales: Daniel Lee, César Leroy, Charlène Crevant, Laure Bonhomme-Coury, Florence Babonneau, Danielle Laurencin, Christian Bonhomme, Gaël De Paëpe
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/32a9adbda9b74b15922d2b5cb897bf63
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spelling oai:doaj.org-article:32a9adbda9b74b15922d2b5cb897bf632021-12-02T14:40:37ZInterfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy10.1038/ncomms141042041-1723https://doaj.org/article/32a9adbda9b74b15922d2b5cb897bf632017-01-01T00:00:00Zhttps://doi.org/10.1038/ncomms14104https://doaj.org/toc/2041-1723Solid-state NMR can in principle be used to study calcium environments in biomaterials such as bones/teeth, but43Ca lacks receptivity. Here the authors present an approach to acquire 43Ca data for hydroxyapatite at its natural isotopic abundance, distinguishing between core and surface Ca sites.Daniel LeeCésar LeroyCharlène CrevantLaure Bonhomme-CouryFlorence BabonneauDanielle LaurencinChristian BonhommeGaël De PaëpeNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Daniel Lee
César Leroy
Charlène Crevant
Laure Bonhomme-Coury
Florence Babonneau
Danielle Laurencin
Christian Bonhomme
Gaël De Paëpe
Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy
description Solid-state NMR can in principle be used to study calcium environments in biomaterials such as bones/teeth, but43Ca lacks receptivity. Here the authors present an approach to acquire 43Ca data for hydroxyapatite at its natural isotopic abundance, distinguishing between core and surface Ca sites.
format article
author Daniel Lee
César Leroy
Charlène Crevant
Laure Bonhomme-Coury
Florence Babonneau
Danielle Laurencin
Christian Bonhomme
Gaël De Paëpe
author_facet Daniel Lee
César Leroy
Charlène Crevant
Laure Bonhomme-Coury
Florence Babonneau
Danielle Laurencin
Christian Bonhomme
Gaël De Paëpe
author_sort Daniel Lee
title Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy
title_short Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy
title_full Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy
title_fullStr Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy
title_full_unstemmed Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy
title_sort interfacial ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43ca nmr spectroscopy
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/32a9adbda9b74b15922d2b5cb897bf63
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AT cesarleroy interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
AT charlenecrevant interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
AT laurebonhommecoury interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
AT florencebabonneau interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
AT daniellelaurencin interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
AT christianbonhomme interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
AT gaeldepaepe interfacialca2environmentsinnanocrystallineapatitesrevealedbydynamicnuclearpolarizationenhanced43canmrspectroscopy
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