Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet
Suppression of quantum tunneling in molecular magnets is key for their magnetic behaviours to be exploitable. Here, the authors show that tuning the geometry of lanthanide single-ion magnets leads to a suppression of the quantum tunneling, finding a three-fold reduction of the tunnel splitting upon...
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Nature Portfolio
2018
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oai:doaj.org-article:32ec8e9f2006483f8d984108a8438cc32021-12-02T14:40:31ZChemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet10.1038/s41467-018-03706-x2041-1723https://doaj.org/article/32ec8e9f2006483f8d984108a8438cc32018-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03706-xhttps://doaj.org/toc/2041-1723Suppression of quantum tunneling in molecular magnets is key for their magnetic behaviours to be exploitable. Here, the authors show that tuning the geometry of lanthanide single-ion magnets leads to a suppression of the quantum tunneling, finding a three-fold reduction of the tunnel splitting upon changing the crystal field symmetry.Mikkel A. SørensenUrsula B. HansenMauro PerfettiKasper S. PedersenElena BartoloméGiovanna G. SimeoniHannu MutkaStéphane RolsMinki JeongIvica ZivkovicMaria RetuertoAna ArauzoJuan BartoloméStergios PiligkosHøgni WeiheLinda H. DoerrerJoris van SlagerenHenrik M. RønnowKim LefmannJesper BendixNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018) |
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EN |
| topic |
Science Q |
| spellingShingle |
Science Q Mikkel A. Sørensen Ursula B. Hansen Mauro Perfetti Kasper S. Pedersen Elena Bartolomé Giovanna G. Simeoni Hannu Mutka Stéphane Rols Minki Jeong Ivica Zivkovic Maria Retuerto Ana Arauzo Juan Bartolomé Stergios Piligkos Høgni Weihe Linda H. Doerrer Joris van Slageren Henrik M. Rønnow Kim Lefmann Jesper Bendix Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| description |
Suppression of quantum tunneling in molecular magnets is key for their magnetic behaviours to be exploitable. Here, the authors show that tuning the geometry of lanthanide single-ion magnets leads to a suppression of the quantum tunneling, finding a three-fold reduction of the tunnel splitting upon changing the crystal field symmetry. |
| format |
article |
| author |
Mikkel A. Sørensen Ursula B. Hansen Mauro Perfetti Kasper S. Pedersen Elena Bartolomé Giovanna G. Simeoni Hannu Mutka Stéphane Rols Minki Jeong Ivica Zivkovic Maria Retuerto Ana Arauzo Juan Bartolomé Stergios Piligkos Høgni Weihe Linda H. Doerrer Joris van Slageren Henrik M. Rønnow Kim Lefmann Jesper Bendix |
| author_facet |
Mikkel A. Sørensen Ursula B. Hansen Mauro Perfetti Kasper S. Pedersen Elena Bartolomé Giovanna G. Simeoni Hannu Mutka Stéphane Rols Minki Jeong Ivica Zivkovic Maria Retuerto Ana Arauzo Juan Bartolomé Stergios Piligkos Høgni Weihe Linda H. Doerrer Joris van Slageren Henrik M. Rønnow Kim Lefmann Jesper Bendix |
| author_sort |
Mikkel A. Sørensen |
| title |
Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| title_short |
Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| title_full |
Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| title_fullStr |
Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| title_full_unstemmed |
Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| title_sort |
chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet |
| publisher |
Nature Portfolio |
| publishDate |
2018 |
| url |
https://doaj.org/article/32ec8e9f2006483f8d984108a8438cc3 |
| work_keys_str_mv |
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| _version_ |
1718390227756646400 |