High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal

Recently, biomass-based materials have attracted increasing attention because of their advantages of low cost, environment-friendly and nonpollution. Herein, the feasibility of using corn stalk biomass fiber (CF) and Fe<sub>3</sub>O<sub>4</sub> embedded chitosan (CS) as a nov...

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Autores principales: Weinan Xing, Qi Liu, Jingyi Wang, Siye Xia, Li Ma, Ran Lu, Yujing Zhang, Yudong Huang, Guangyu Wu
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:3367e2c174c549bbbfdeb9030f8cad692021-11-25T18:31:07ZHigh Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal10.3390/nano111129502079-4991https://doaj.org/article/3367e2c174c549bbbfdeb9030f8cad692021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/2950https://doaj.org/toc/2079-4991Recently, biomass-based materials have attracted increasing attention because of their advantages of low cost, environment-friendly and nonpollution. Herein, the feasibility of using corn stalk biomass fiber (CF) and Fe<sub>3</sub>O<sub>4</sub> embedded chitosan (CS) as a novel biomass-based adsorbent (CFS) to remove chloramphenicol (CAPC) from aqueous solution. Structure of CFS was characterized by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM) and zeta potential techniques. The effects of solution pH, adsorption time and ion strength on the adsorption capacity were examined. Adsorption isotherms obtained from batch experiments were better fitted by Langmuir model compared with Freundlich model, Dubinin–Radushkevich model and Temkin model. Adsorption kinetic data matched well to the pseudo-second order kinetic model. CAPC adsorption was endothermic, spontaneous, and entropy-increasing nature on CFS. In addition, the CFS could be separated by an external magnetic field, recycled, and reused without any significant loss in the adsorption capacity of CAPC. Based on these excellent performances, there is potential that CFS can be considered as a proficient and economically suitable material for the CAPC removal from the water environment.Weinan XingQi LiuJingyi WangSiye XiaLi MaRan LuYujing ZhangYudong HuangGuangyu WuMDPI AGarticlebiomassagricultural wastechloramphenicol removaladsorptionChemistryQD1-999ENNanomaterials, Vol 11, Iss 2950, p 2950 (2021)
institution DOAJ
collection DOAJ
language EN
topic biomass
agricultural waste
chloramphenicol removal
adsorption
Chemistry
QD1-999
spellingShingle biomass
agricultural waste
chloramphenicol removal
adsorption
Chemistry
QD1-999
Weinan Xing
Qi Liu
Jingyi Wang
Siye Xia
Li Ma
Ran Lu
Yujing Zhang
Yudong Huang
Guangyu Wu
High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal
description Recently, biomass-based materials have attracted increasing attention because of their advantages of low cost, environment-friendly and nonpollution. Herein, the feasibility of using corn stalk biomass fiber (CF) and Fe<sub>3</sub>O<sub>4</sub> embedded chitosan (CS) as a novel biomass-based adsorbent (CFS) to remove chloramphenicol (CAPC) from aqueous solution. Structure of CFS was characterized by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM) and zeta potential techniques. The effects of solution pH, adsorption time and ion strength on the adsorption capacity were examined. Adsorption isotherms obtained from batch experiments were better fitted by Langmuir model compared with Freundlich model, Dubinin–Radushkevich model and Temkin model. Adsorption kinetic data matched well to the pseudo-second order kinetic model. CAPC adsorption was endothermic, spontaneous, and entropy-increasing nature on CFS. In addition, the CFS could be separated by an external magnetic field, recycled, and reused without any significant loss in the adsorption capacity of CAPC. Based on these excellent performances, there is potential that CFS can be considered as a proficient and economically suitable material for the CAPC removal from the water environment.
format article
author Weinan Xing
Qi Liu
Jingyi Wang
Siye Xia
Li Ma
Ran Lu
Yujing Zhang
Yudong Huang
Guangyu Wu
author_facet Weinan Xing
Qi Liu
Jingyi Wang
Siye Xia
Li Ma
Ran Lu
Yujing Zhang
Yudong Huang
Guangyu Wu
author_sort Weinan Xing
title High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal
title_short High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal
title_full High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal
title_fullStr High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal
title_full_unstemmed High Selectivity and Reusability of Biomass-Based Adsorbent for Chloramphenicol Removal
title_sort high selectivity and reusability of biomass-based adsorbent for chloramphenicol removal
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/3367e2c174c549bbbfdeb9030f8cad69
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