Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

Hydrogen borrowing is an attractive method for C-N bond formation - avoiding multiple alkylation products and reducing waste - but often is carried out with noble metals. Here the authors show that a manganese catalyst allows the selective N-alkylation of amines with alcohols.

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Autores principales:	Saravanakumar Elangovan, Jacob Neumann, Jean-Baptiste Sortais, Kathrin Junge, Christophe Darcel, Matthias Beller
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/337ca5d76b314e3fb110d3242a4df67e
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spelling	oai:doaj.org-article:337ca5d76b314e3fb110d3242a4df67e2021-12-02T16:57:03ZEfficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes10.1038/ncomms126412041-1723https://doaj.org/article/337ca5d76b314e3fb110d3242a4df67e2016-10-01T00:00:00Zhttps://doi.org/10.1038/ncomms12641https://doaj.org/toc/2041-1723Hydrogen borrowing is an attractive method for C-N bond formation - avoiding multiple alkylation products and reducing waste - but often is carried out with noble metals. Here the authors show that a manganese catalyst allows the selective N-alkylation of amines with alcohols.Saravanakumar ElangovanJacob NeumannJean-Baptiste SortaisKathrin JungeChristophe DarcelMatthias BellerNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Saravanakumar Elangovan Jacob Neumann Jean-Baptiste Sortais Kathrin Junge Christophe Darcel Matthias Beller Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
description	Hydrogen borrowing is an attractive method for C-N bond formation - avoiding multiple alkylation products and reducing waste - but often is carried out with noble metals. Here the authors show that a manganese catalyst allows the selective N-alkylation of amines with alcohols.
format	article
author	Saravanakumar Elangovan Jacob Neumann Jean-Baptiste Sortais Kathrin Junge Christophe Darcel Matthias Beller
author_facet	Saravanakumar Elangovan Jacob Neumann Jean-Baptiste Sortais Kathrin Junge Christophe Darcel Matthias Beller
author_sort	Saravanakumar Elangovan
title	Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
title_short	Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
title_full	Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
title_fullStr	Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
title_full_unstemmed	Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
title_sort	efficient and selective n-alkylation of amines with alcohols catalysed by manganese pincer complexes
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/337ca5d76b314e3fb110d3242a4df67e
work_keys_str_mv	AT saravanakumarelangovan efficientandselectivenalkylationofamineswithalcoholscatalysedbymanganesepincercomplexes AT jacobneumann efficientandselectivenalkylationofamineswithalcoholscatalysedbymanganesepincercomplexes AT jeanbaptistesortais efficientandselectivenalkylationofamineswithalcoholscatalysedbymanganesepincercomplexes AT kathrinjunge efficientandselectivenalkylationofamineswithalcoholscatalysedbymanganesepincercomplexes AT christophedarcel efficientandselectivenalkylationofamineswithalcoholscatalysedbymanganesepincercomplexes AT matthiasbeller efficientandselectivenalkylationofamineswithalcoholscatalysedbymanganesepincercomplexes
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Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

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