Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

Converting dinitrogen into other nitrogen compounds such as ammonia is a difficult task, especially under mild conditions. Here, the authors report a molecular iron complex capable of reducing dinitrogen to both ammonia and hydrazine in a catalytic process.

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Autores principales: Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima, Yuki Matsuo, Hiromasa Tanaka, Kazuyuki Ishii, Kazunari Yoshizawa, Yoshiaki Nishibayashi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/33ba2d98c375476682dbd60b29a2b752
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Sumario:Converting dinitrogen into other nitrogen compounds such as ammonia is a difficult task, especially under mild conditions. Here, the authors report a molecular iron complex capable of reducing dinitrogen to both ammonia and hydrazine in a catalytic process.