Influence of l-quebrachitol on the properties of centrifuged natural rubber

Nonrubber components (NRCs) play an important role in the outstanding mechanical property of natural rubber (NR). The main inositol component of NRCs in natural rubber latex (NRL) is l-quebrachitol. In this study, the influence of l-quebrachitol on the properties of centrifuged natural rubber (CNR)...

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Autores principales: Hu Benxiang, Zhou Yuanbing, Luo Ming-Chao, Wei Yan-Chan, Liu Gui-Xiang, Liao Shuangquan, Zhao Yanfang
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Lenguaje:EN
Publicado: De Gruyter 2021
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Acceso en línea:https://doaj.org/article/33d216d8e417404e88abfbab74388944
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spelling oai:doaj.org-article:33d216d8e417404e88abfbab743889442021-12-05T14:10:47ZInfluence of l-quebrachitol on the properties of centrifuged natural rubber1618-722910.1515/epoly-2021-0042https://doaj.org/article/33d216d8e417404e88abfbab743889442021-05-01T00:00:00Zhttps://doi.org/10.1515/epoly-2021-0042https://doaj.org/toc/1618-7229Nonrubber components (NRCs) play an important role in the outstanding mechanical property of natural rubber (NR). The main inositol component of NRCs in natural rubber latex (NRL) is l-quebrachitol. In this study, the influence of l-quebrachitol on the properties of centrifuged natural rubber (CNR) was investigated. The NRL was centrifuged twice to remove most of the NRCs. After that, l-quebrachitol was added in the latex with per hundreds of rubber (phr) vary from 0% to 0.8%, and the vulcanized CNR were prepared. It is shown that the properties of vulcanized CNR were greatly changed, with T 90 reduced from 19 to 15 min, the tensile strength increased from 5 to 9 MPa, T g reduced by about 2°C, and the ability for strain-induced crystallization was enhanced. It was proved by FTIR results that l-quebrachitol was linked to the CNR crosslinking network with ester bond.Hu BenxiangZhou YuanbingLuo Ming-ChaoWei Yan-ChanLiu Gui-XiangLiao ShuangquanZhao YanfangDe Gruyterarticlenatural rubbernon-rubber componentsl-quebrachitolcentrifuged natural rubbervulcanization networkPolymers and polymer manufactureTP1080-1185ENe-Polymers, Vol 21, Iss 1, Pp 420-427 (2021)
institution DOAJ
collection DOAJ
language EN
topic natural rubber
non-rubber components
l-quebrachitol
centrifuged natural rubber
vulcanization network
Polymers and polymer manufacture
TP1080-1185
spellingShingle natural rubber
non-rubber components
l-quebrachitol
centrifuged natural rubber
vulcanization network
Polymers and polymer manufacture
TP1080-1185
Hu Benxiang
Zhou Yuanbing
Luo Ming-Chao
Wei Yan-Chan
Liu Gui-Xiang
Liao Shuangquan
Zhao Yanfang
Influence of l-quebrachitol on the properties of centrifuged natural rubber
description Nonrubber components (NRCs) play an important role in the outstanding mechanical property of natural rubber (NR). The main inositol component of NRCs in natural rubber latex (NRL) is l-quebrachitol. In this study, the influence of l-quebrachitol on the properties of centrifuged natural rubber (CNR) was investigated. The NRL was centrifuged twice to remove most of the NRCs. After that, l-quebrachitol was added in the latex with per hundreds of rubber (phr) vary from 0% to 0.8%, and the vulcanized CNR were prepared. It is shown that the properties of vulcanized CNR were greatly changed, with T 90 reduced from 19 to 15 min, the tensile strength increased from 5 to 9 MPa, T g reduced by about 2°C, and the ability for strain-induced crystallization was enhanced. It was proved by FTIR results that l-quebrachitol was linked to the CNR crosslinking network with ester bond.
format article
author Hu Benxiang
Zhou Yuanbing
Luo Ming-Chao
Wei Yan-Chan
Liu Gui-Xiang
Liao Shuangquan
Zhao Yanfang
author_facet Hu Benxiang
Zhou Yuanbing
Luo Ming-Chao
Wei Yan-Chan
Liu Gui-Xiang
Liao Shuangquan
Zhao Yanfang
author_sort Hu Benxiang
title Influence of l-quebrachitol on the properties of centrifuged natural rubber
title_short Influence of l-quebrachitol on the properties of centrifuged natural rubber
title_full Influence of l-quebrachitol on the properties of centrifuged natural rubber
title_fullStr Influence of l-quebrachitol on the properties of centrifuged natural rubber
title_full_unstemmed Influence of l-quebrachitol on the properties of centrifuged natural rubber
title_sort influence of l-quebrachitol on the properties of centrifuged natural rubber
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/33d216d8e417404e88abfbab74388944
work_keys_str_mv AT hubenxiang influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
AT zhouyuanbing influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
AT luomingchao influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
AT weiyanchan influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
AT liuguixiang influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
AT liaoshuangquan influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
AT zhaoyanfang influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber
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