Influence of l-quebrachitol on the properties of centrifuged natural rubber
Nonrubber components (NRCs) play an important role in the outstanding mechanical property of natural rubber (NR). The main inositol component of NRCs in natural rubber latex (NRL) is l-quebrachitol. In this study, the influence of l-quebrachitol on the properties of centrifuged natural rubber (CNR)...
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De Gruyter
2021
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oai:doaj.org-article:33d216d8e417404e88abfbab743889442021-12-05T14:10:47ZInfluence of l-quebrachitol on the properties of centrifuged natural rubber1618-722910.1515/epoly-2021-0042https://doaj.org/article/33d216d8e417404e88abfbab743889442021-05-01T00:00:00Zhttps://doi.org/10.1515/epoly-2021-0042https://doaj.org/toc/1618-7229Nonrubber components (NRCs) play an important role in the outstanding mechanical property of natural rubber (NR). The main inositol component of NRCs in natural rubber latex (NRL) is l-quebrachitol. In this study, the influence of l-quebrachitol on the properties of centrifuged natural rubber (CNR) was investigated. The NRL was centrifuged twice to remove most of the NRCs. After that, l-quebrachitol was added in the latex with per hundreds of rubber (phr) vary from 0% to 0.8%, and the vulcanized CNR were prepared. It is shown that the properties of vulcanized CNR were greatly changed, with T 90 reduced from 19 to 15 min, the tensile strength increased from 5 to 9 MPa, T g reduced by about 2°C, and the ability for strain-induced crystallization was enhanced. It was proved by FTIR results that l-quebrachitol was linked to the CNR crosslinking network with ester bond.Hu BenxiangZhou YuanbingLuo Ming-ChaoWei Yan-ChanLiu Gui-XiangLiao ShuangquanZhao YanfangDe Gruyterarticlenatural rubbernon-rubber componentsl-quebrachitolcentrifuged natural rubbervulcanization networkPolymers and polymer manufactureTP1080-1185ENe-Polymers, Vol 21, Iss 1, Pp 420-427 (2021) |
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DOAJ |
language |
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topic |
natural rubber non-rubber components l-quebrachitol centrifuged natural rubber vulcanization network Polymers and polymer manufacture TP1080-1185 |
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natural rubber non-rubber components l-quebrachitol centrifuged natural rubber vulcanization network Polymers and polymer manufacture TP1080-1185 Hu Benxiang Zhou Yuanbing Luo Ming-Chao Wei Yan-Chan Liu Gui-Xiang Liao Shuangquan Zhao Yanfang Influence of l-quebrachitol on the properties of centrifuged natural rubber |
description |
Nonrubber components (NRCs) play an important role in the outstanding mechanical property of natural rubber (NR). The main inositol component of NRCs in natural rubber latex (NRL) is l-quebrachitol. In this study, the influence of l-quebrachitol on the properties of centrifuged natural rubber (CNR) was investigated. The NRL was centrifuged twice to remove most of the NRCs. After that, l-quebrachitol was added in the latex with per hundreds of rubber (phr) vary from 0% to 0.8%, and the vulcanized CNR were prepared. It is shown that the properties of vulcanized CNR were greatly changed, with T
90 reduced from 19 to 15 min, the tensile strength increased from 5 to 9 MPa, T
g reduced by about 2°C, and the ability for strain-induced crystallization was enhanced. It was proved by FTIR results that l-quebrachitol was linked to the CNR crosslinking network with ester bond. |
format |
article |
author |
Hu Benxiang Zhou Yuanbing Luo Ming-Chao Wei Yan-Chan Liu Gui-Xiang Liao Shuangquan Zhao Yanfang |
author_facet |
Hu Benxiang Zhou Yuanbing Luo Ming-Chao Wei Yan-Chan Liu Gui-Xiang Liao Shuangquan Zhao Yanfang |
author_sort |
Hu Benxiang |
title |
Influence of l-quebrachitol on the properties of centrifuged natural rubber |
title_short |
Influence of l-quebrachitol on the properties of centrifuged natural rubber |
title_full |
Influence of l-quebrachitol on the properties of centrifuged natural rubber |
title_fullStr |
Influence of l-quebrachitol on the properties of centrifuged natural rubber |
title_full_unstemmed |
Influence of l-quebrachitol on the properties of centrifuged natural rubber |
title_sort |
influence of l-quebrachitol on the properties of centrifuged natural rubber |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/33d216d8e417404e88abfbab74388944 |
work_keys_str_mv |
AT hubenxiang influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber AT zhouyuanbing influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber AT luomingchao influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber AT weiyanchan influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber AT liuguixiang influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber AT liaoshuangquan influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber AT zhaoyanfang influenceoflquebrachitolonthepropertiesofcentrifugednaturalrubber |
_version_ |
1718371713290338304 |