Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts

Abstract  The catalytic cracking conversion of Iraqi vacuum gas oil was studied on large and medium pore size (HY, HX, ZSM-22 and ZSM-11) of zeolite catalysts. These catalysts were prepared locally and used in the present work. The catalytic conversion performed on a continuous fixed-bed laborat...

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Autores principales: Ameel Mohammed Rahman, Mohanned H. Salman, Khalid Waleed Hammed
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Publicado: Al-Khwarizmi College of Engineering – University of Baghdad 2014
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Acceso en línea:https://doaj.org/article/34158c954b3043bdaa225f3b5e243ab2
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spelling oai:doaj.org-article:34158c954b3043bdaa225f3b5e243ab22021-12-02T02:38:35ZCatalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts1818-11712312-0789https://doaj.org/article/34158c954b3043bdaa225f3b5e243ab22014-12-01T00:00:00Zhttp://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/216https://doaj.org/toc/1818-1171https://doaj.org/toc/2312-0789 Abstract  The catalytic cracking conversion of Iraqi vacuum gas oil was studied on large and medium pore size (HY, HX, ZSM-22 and ZSM-11) of zeolite catalysts. These catalysts were prepared locally and used in the present work. The catalytic conversion performed on a continuous fixed-bed laboratory reaction unit. Experiments were performed in the temperature range of 673 to 823K, pressure range of 3 to 15bar, and LHSV range of 0.5-3h-1. The results show that the catalytic conversion of vacuum gas oil increases with increase in reaction temperature and decreases with increase in LHSV. The catalytic activity for the proposed catalysts arranged in the following order: HY>HX>ZSM-11>ZSM-22 The product distribution depends greatly on the temperature and on the catalyst type. A higher hydrocarbon yields was obtained for HY zeolite catalyst. The selectivity towards high octane number compounds for the proposed catalysts are arranged in the following order: HY>HX>ZSM-11>ZSM-22The cracking conversion is improved by increasing reaction pressure up to 15 bar. The simulated experiments of the catalytic cracking process show that the higher conversion and more desired products can be achieved to conventional feeds. Keywords: catalytic cracking, vacuum gas oil, Zeolite, HY, HX, ZSM-11, ZSM-22. Ameel Mohammed RahmanMohanned H. SalmanKhalid Waleed HammedAl-Khwarizmi College of Engineering – University of Baghdadarticlecatalytic cracking, vacuum gas oil, Zeolite, HY, HX, ZSM-11, ZSM-22.Chemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 11, Iss 1 (2014)
institution DOAJ
collection DOAJ
language EN
topic catalytic cracking, vacuum gas oil, Zeolite, HY, HX, ZSM-11, ZSM-22.
Chemical engineering
TP155-156
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle catalytic cracking, vacuum gas oil, Zeolite, HY, HX, ZSM-11, ZSM-22.
Chemical engineering
TP155-156
Engineering (General). Civil engineering (General)
TA1-2040
Ameel Mohammed Rahman
Mohanned H. Salman
Khalid Waleed Hammed
Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts
description Abstract  The catalytic cracking conversion of Iraqi vacuum gas oil was studied on large and medium pore size (HY, HX, ZSM-22 and ZSM-11) of zeolite catalysts. These catalysts were prepared locally and used in the present work. The catalytic conversion performed on a continuous fixed-bed laboratory reaction unit. Experiments were performed in the temperature range of 673 to 823K, pressure range of 3 to 15bar, and LHSV range of 0.5-3h-1. The results show that the catalytic conversion of vacuum gas oil increases with increase in reaction temperature and decreases with increase in LHSV. The catalytic activity for the proposed catalysts arranged in the following order: HY>HX>ZSM-11>ZSM-22 The product distribution depends greatly on the temperature and on the catalyst type. A higher hydrocarbon yields was obtained for HY zeolite catalyst. The selectivity towards high octane number compounds for the proposed catalysts are arranged in the following order: HY>HX>ZSM-11>ZSM-22The cracking conversion is improved by increasing reaction pressure up to 15 bar. The simulated experiments of the catalytic cracking process show that the higher conversion and more desired products can be achieved to conventional feeds. Keywords: catalytic cracking, vacuum gas oil, Zeolite, HY, HX, ZSM-11, ZSM-22.
format article
author Ameel Mohammed Rahman
Mohanned H. Salman
Khalid Waleed Hammed
author_facet Ameel Mohammed Rahman
Mohanned H. Salman
Khalid Waleed Hammed
author_sort Ameel Mohammed Rahman
title Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts
title_short Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts
title_full Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts
title_fullStr Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts
title_full_unstemmed Catalytic Cracking of Iraqi Vacuum Gasoil Using Large and Medium Pore Size of Zeolite Catalysts
title_sort catalytic cracking of iraqi vacuum gasoil using large and medium pore size of zeolite catalysts
publisher Al-Khwarizmi College of Engineering – University of Baghdad
publishDate 2014
url https://doaj.org/article/34158c954b3043bdaa225f3b5e243ab2
work_keys_str_mv AT ameelmohammedrahman catalyticcrackingofiraqivacuumgasoilusinglargeandmediumporesizeofzeolitecatalysts
AT mohannedhsalman catalyticcrackingofiraqivacuumgasoilusinglargeandmediumporesizeofzeolitecatalysts
AT khalidwaleedhammed catalyticcrackingofiraqivacuumgasoilusinglargeandmediumporesizeofzeolitecatalysts
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