Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum

Thermochemical laser-induced periodic surface structures (TLIPSS) are a relatively new type of periodic structures formed in the focal area of linear polarized laser radiation by the thermally stimulated reaction of oxidation. The high regularity of the structures and the possibility of forming high...

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Autores principales: Dmitrij A. Belousov, Kirill A. Bronnikov, Konstantin A. Okotrub, Sergey L. Mikerin, Victor P. Korolkov, Vadim S. Terentyev, Alexander V. Dostovalov
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:342e3bf0a49c45aaa85bcdebd6ea7a162021-11-11T18:12:30ZThermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum10.3390/ma142167141996-1944https://doaj.org/article/342e3bf0a49c45aaa85bcdebd6ea7a162021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6714https://doaj.org/toc/1996-1944Thermochemical laser-induced periodic surface structures (TLIPSS) are a relatively new type of periodic structures formed in the focal area of linear polarized laser radiation by the thermally stimulated reaction of oxidation. The high regularity of the structures and the possibility of forming high-ordered structures over a large area open up possibilities for the practical application for changing the optical and physical properties of materials surface. Since the mechanism of formation of these structures is based on a chemical oxidation reaction, an intriguing question involves the influence of air pressure on the quality of structure formation. This paper presents the results on the TLIPSS formation on a thin hafnium film with fs IR laser radiation at various ambient air pressures from 4 Torr to 760 Torr. Despite the decrease in the oxygen content in the ambient environment by two orders of magnitude, the formation of high-ordered TLIPSS (dispersion in the LIPSS orientation angle δθ < 5°) with a period of ≈700 nm occurs within a wide range of parameters variation (laser power, scanning speed). This behavior of TLIPSS formation is in agreement with experimental data obtained earlier on the study of the kinetics of high-temperature oxidation of hafnium at various oxygen pressures.Dmitrij A. BelousovKirill A. BronnikovKonstantin A. OkotrubSergey L. MikerinVictor P. KorolkovVadim S. TerentyevAlexander V. DostovalovMDPI AGarticlelaser-induced periodic surface structureshafnium filmsdigital image processingmicroscopylaser materials processingTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6714, p 6714 (2021)
institution DOAJ
collection DOAJ
language EN
topic laser-induced periodic surface structures
hafnium films
digital image processing
microscopy
laser materials processing
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle laser-induced periodic surface structures
hafnium films
digital image processing
microscopy
laser materials processing
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Dmitrij A. Belousov
Kirill A. Bronnikov
Konstantin A. Okotrub
Sergey L. Mikerin
Victor P. Korolkov
Vadim S. Terentyev
Alexander V. Dostovalov
Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum
description Thermochemical laser-induced periodic surface structures (TLIPSS) are a relatively new type of periodic structures formed in the focal area of linear polarized laser radiation by the thermally stimulated reaction of oxidation. The high regularity of the structures and the possibility of forming high-ordered structures over a large area open up possibilities for the practical application for changing the optical and physical properties of materials surface. Since the mechanism of formation of these structures is based on a chemical oxidation reaction, an intriguing question involves the influence of air pressure on the quality of structure formation. This paper presents the results on the TLIPSS formation on a thin hafnium film with fs IR laser radiation at various ambient air pressures from 4 Torr to 760 Torr. Despite the decrease in the oxygen content in the ambient environment by two orders of magnitude, the formation of high-ordered TLIPSS (dispersion in the LIPSS orientation angle δθ < 5°) with a period of ≈700 nm occurs within a wide range of parameters variation (laser power, scanning speed). This behavior of TLIPSS formation is in agreement with experimental data obtained earlier on the study of the kinetics of high-temperature oxidation of hafnium at various oxygen pressures.
format article
author Dmitrij A. Belousov
Kirill A. Bronnikov
Konstantin A. Okotrub
Sergey L. Mikerin
Victor P. Korolkov
Vadim S. Terentyev
Alexander V. Dostovalov
author_facet Dmitrij A. Belousov
Kirill A. Bronnikov
Konstantin A. Okotrub
Sergey L. Mikerin
Victor P. Korolkov
Vadim S. Terentyev
Alexander V. Dostovalov
author_sort Dmitrij A. Belousov
title Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum
title_short Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum
title_full Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum
title_fullStr Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum
title_full_unstemmed Thermochemical Laser-Induced Periodic Surface Structures Formation by Femtosecond Laser on Hf Thin Films in Air and Vacuum
title_sort thermochemical laser-induced periodic surface structures formation by femtosecond laser on hf thin films in air and vacuum
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/342e3bf0a49c45aaa85bcdebd6ea7a16
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