Selective reduction and homologation of carbon monoxide by organometallic iron complexes

Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and iron carboxylates under mild conditions.

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Autores principales:	Helen R. Sharpe, Ana M. Geer, Laurence J. Taylor, Benjamin M. Gridley, Toby J. Blundell, Alexander J. Blake, E. Stephen Davies, William Lewis, Jonathan McMaster, David Robinson, Deborah L. Kays
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/345eb1f0dbd64225b086da22de3b273c
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spelling	oai:doaj.org-article:345eb1f0dbd64225b086da22de3b273c2021-12-02T14:40:32ZSelective reduction and homologation of carbon monoxide by organometallic iron complexes10.1038/s41467-018-06242-w2041-1723https://doaj.org/article/345eb1f0dbd64225b086da22de3b273c2018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06242-whttps://doaj.org/toc/2041-1723Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and iron carboxylates under mild conditions.Helen R. SharpeAna M. GeerLaurence J. TaylorBenjamin M. GridleyToby J. BlundellAlexander J. BlakeE. Stephen DaviesWilliam LewisJonathan McMasterDavid RobinsonDeborah L. KaysNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Helen R. Sharpe Ana M. Geer Laurence J. Taylor Benjamin M. Gridley Toby J. Blundell Alexander J. Blake E. Stephen Davies William Lewis Jonathan McMaster David Robinson Deborah L. Kays Selective reduction and homologation of carbon monoxide by organometallic iron complexes
description	Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and iron carboxylates under mild conditions.
format	article
author	Helen R. Sharpe Ana M. Geer Laurence J. Taylor Benjamin M. Gridley Toby J. Blundell Alexander J. Blake E. Stephen Davies William Lewis Jonathan McMaster David Robinson Deborah L. Kays
author_facet	Helen R. Sharpe Ana M. Geer Laurence J. Taylor Benjamin M. Gridley Toby J. Blundell Alexander J. Blake E. Stephen Davies William Lewis Jonathan McMaster David Robinson Deborah L. Kays
author_sort	Helen R. Sharpe
title	Selective reduction and homologation of carbon monoxide by organometallic iron complexes
title_short	Selective reduction and homologation of carbon monoxide by organometallic iron complexes
title_full	Selective reduction and homologation of carbon monoxide by organometallic iron complexes
title_fullStr	Selective reduction and homologation of carbon monoxide by organometallic iron complexes
title_full_unstemmed	Selective reduction and homologation of carbon monoxide by organometallic iron complexes
title_sort	selective reduction and homologation of carbon monoxide by organometallic iron complexes
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/345eb1f0dbd64225b086da22de3b273c
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Selective reduction and homologation of carbon monoxide by organometallic iron complexes

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